deuterooxonium perchlorate | 24847-50-5

• 英文名称: deuterooxonium perchlorate
• 英文别名: perchloric acid monohydrate
• CAS: 24847-50-5
• 化学式: ClHO₄*H₂O
• 分子量: 121.45
• InChiKey: AIUIJBDEQKTMHT-ZRLBSURWSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -4.95
• 重原子数：
  6.0
• 可旋转键数：
  1.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  120.91
• 氢给体数：
  1.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  氮 、 deuterooxonium perchlorate 以 neat (no solvent) 为溶剂， 生成
  参考文献：
  名称：

  Thermal Expansivity of Ionic Clathrate Hydrates Including Gaseous Guest Molecules

  摘要：

  lthough thermal expansion is a key factor in relation to the host guest interaction of clathrate hydrates, few studies have investigated the thermal behavior of ionic clathrate hydrates. The existence of ionic species in these hydrates creates a unique host guest interaction compared. to that of nonionic clathrate hydrates. It was revealed that X-ray diffraction cannot be used for research of tetramethylammonium hydroxide clathrate hydrates due to damage of the cations by the X-ray, which results in abnormal thermal expansion of the ionic clathrate hydrates. Hence, in the pres-ent work, the thermal expansivities of binary sII Me4NOD - 16D(2)O and sI DClO4 center dot 5.5D(2)O were measured by neutron powder diffraction (NPD) in order to shed light on their thermal behavior. General correlations for the thermal behaviors of given structures were established and lattice expansions depending on the guests were compared between ionic and nonionic clathrate hydrates. The peculiar change in the thermal expansivity of binary DClO4 center dot 5.5D(2)O was also considered in relation to the host guest configuration.

  DOI：

  10.1021/jp110737q
• 作为产物：
  描述：

  deuterooxonium perchlorate 、 重水 生成 deuterooxonium perchlorate
  参考文献：
  名称：

  Karelin, Russian Journal of Inorganic Chemistry, 2002, vol. 47, # 10, p. 1541 - 1550

  摘要：

  DOI：

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Cl: SVol.B2, 50, page 423 - 425
  作者：

  DOI：——

  日期：——
• Smith, G. F.; Diehl, H., Anal. Chem. Proc. Intern. Symp. Birmingham Univ., Birmingham, Engl., 1962 (1963), S. 394/6
  作者：Smith, G. F.、Diehl, H.

  DOI：——

  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Cl: SVol.B2, 56, page 437 - 440
  作者：

  DOI：——

  日期：——