[ZnNd(N,N'-bis(3-methoxysalicylidene)ethylene-1,2-diamine)(H2O)(NO3)3] | 430431-16-6

• 英文名称: [ZnNd(N,N'-bis(3-methoxysalicylidene)ethylene-1,2-diamine)(H2O)(NO3)3]
• CAS: 430431-16-6；1009735-97-0
• 化学式: C₁₈H₂₀N₅NdO₁₄Zn
• 分子量: 740.012
• InChiKey: KLAJYAOYEUOWPM-FBRZHQNCSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
  None
• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [ZnNd(N,N'-bis(3-methoxysalicylidene)ethylene-1,2-diamine)(H2O)(NO3)3] 、 disodium terephthalate 以 乙醇 为溶剂， 以30%的产率得到[Zn4Nd2(N,N'-bis(3-methoxysalicylidene)ethylene-1,2-diamine-H2)4(1,4-benzenedicarboxylate)]*[ZnNd(N,N'-bis(3-methoxysalicylidene)ethylene-1,2-diamine-H2)(NO3)3(OAc)]2
  参考文献：
  名称：

  Multinuclear NIR luminescent 1,4-BDC bridged Schiff-base complexes of Nd(III)

  摘要：

  Solvent and reaction stoichiometry dictate the products isolated from reactions of the dinuclear precursor complex [ZnNdL(H2O)(NO3)(3)] (H2L=N,N'-bis(3-methoxy-salicylidene)ethylene-1,2-diamine) with the anionic multidentate linker 1,4-benzenedicarboxylate (1,4-BDC). With a 2:1 molar ratio of ZnNd:Na(2)1,4-BDC in CH3CN-EtOH the tetranuclear complex [Zn2Nd2L2(1,4-BDC)(NO3)(4)(EtOH)(2)] center dot 2MeCN (1) is produced while hexanuclear [Zn4Nd2L4(1,4-BDC)(2)] center dot (NO3)(2) center dot 2Et(2)O center dot 4H(2)O (2) can be isolated from a DMF-EtOH mixture. A 4:1 mole ratio in DMF-EtOH gave the unusual polynuclear complex [Zn4Nd2L4(1,4-BDC)(2)] center dot [ZnNdL(NO3)(3)(OAc)](2) (3). The NIR photophysical properties of the new compounds are reported. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2008.09.014
• 作为产物：
  描述：

  neodymium(III) nitrate hexahydrate 、 N,N'-bis(3-methoxysalicylidene)ethylenediamine 、 zinc(II) acetate dihydrate 以 乙醇 为溶剂， 生成 [ZnNd(N,N'-bis(3-methoxysalicylidene)ethylene-1,2-diamine)(H2O)(NO3)3]
  参考文献：
  名称：

  Multinuclear NIR luminescent 1,4-BDC bridged Schiff-base complexes of Nd(III)

  摘要：

  Solvent and reaction stoichiometry dictate the products isolated from reactions of the dinuclear precursor complex [ZnNdL(H2O)(NO3)(3)] (H2L=N,N'-bis(3-methoxy-salicylidene)ethylene-1,2-diamine) with the anionic multidentate linker 1,4-benzenedicarboxylate (1,4-BDC). With a 2:1 molar ratio of ZnNd:Na(2)1,4-BDC in CH3CN-EtOH the tetranuclear complex [Zn2Nd2L2(1,4-BDC)(NO3)(4)(EtOH)(2)] center dot 2MeCN (1) is produced while hexanuclear [Zn4Nd2L4(1,4-BDC)(2)] center dot (NO3)(2) center dot 2Et(2)O center dot 4H(2)O (2) can be isolated from a DMF-EtOH mixture. A 4:1 mole ratio in DMF-EtOH gave the unusual polynuclear complex [Zn4Nd2L4(1,4-BDC)(2)] center dot [ZnNdL(NO3)(3)(OAc)](2) (3). The NIR photophysical properties of the new compounds are reported. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2008.09.014