1,10-phenanthroline-2,9-{o-CH2OCH2C6H4(CH3)(Cr(CO)3)}2 | 124913-26-4

• 英文名称: 1,10-phenanthroline-2,9-{o-CH2OCH2C6H4(CH3)(Cr(CO)3)}2
• CAS: 124913-26-4；133815-48-2；124990-35-8
• 化学式: C₃₆H₂₈Cr₂N₂O₈
• 分子量: 720.619
• InChiKey: NVZIMNBYANZSNO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  copper(I) trifluoromethanesulfonate benzene 、 1,10-phenanthroline-2,9-{o-CH2OCH2C6H4(CH3)(Cr(CO)3)}2 以 二氯甲烷 为溶剂， 以81%的产率得到
  参考文献：
  名称：

  Influence of arenechromium tricarbonyl on the redox behavior of copper in new heteropentanuclear complexes prepared from functionalized phenanthroline tweezer ligands

  摘要：

  Novel mixed [Cu(4a-c)2]CF3SO3 pentanuclear copper(I)/chromium(0) complexes containing tweezer ligands that contain, within the same molecule, a 2,9-disubstituted-1,10-phenanthroline and two arene-chromium subunits. The mononuclear copper(I) complexes [Cu(5a-c)2] CF3SO3 have been prepared from the chromium free ligand species 5a-c, obtained by quantitative photochemical decomplexation of the parent species 4a-c. Cyclic voltammetry showed that in these complexes copper(I) can be reversibly oxidized to copper(II) in CH2Cl2. The Cu(II/I) couples are more positive in the presence of the four surrounding redox-active arenechromium subunits, revealing an electron-withdrawing effect. Complexes [Cu(4c)2]+, [Cu(5c)2]+ form new species (1:1 ligand copper stoichiometry) upon addition of excess [Cu(CH3CN)4]+, which were identified electrochemically and by FAB+ mass spectroscopy.

  DOI：

  10.1016/0022-328x(91)86241-h
• 作为产物：
  描述：

  (o-methylbenzylalcohol)chromiumtricarbonyl sodium salt 、 2,9-bis-(bromomethyl)-1,10-phenantroline 以 四氢呋喃 为溶剂， 以40%的产率得到1,10-phenanthroline-2,9-{o-CH2OCH2C6H4(CH3)(Cr(CO)3)}2
  参考文献：
  名称：

  Design, synthesis and heerotrimetallic complexes of functionalization tweezer ligands

  摘要：

  DOI：

  10.1016/0022-328x(89)85440-3