mer-[RuCl₃(dimethyl sulfoxide)(2,2'-bipyridyl)] | 1000163-55-2

• 英文名称: mer-[RuCl₃(dimethyl sulfoxide)(2,2'-bipyridyl)]
• 英文别名: mer-[RuCl₃(dmso)(bpy)]；mer-[RuCl3(DMSO)(2,2'-bipyridine)]
• CAS: 1000163-55-2；119693-56-0
• 化学式: C₁₂H₁₄Cl₃N₂ORuS
• 分子量: 441.751
• InChiKey: IXDNDGXTFLBYRB-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  mer-[RuCl₃(dimethyl sulfoxide)(2,2'-bipyridyl)] 、 一氧化碳 以 1,2-二氯乙烷 为溶剂， 以47%的产率得到mer-[RuCl2(DMSO)(CO)(2,2'-bipyridine)]
  参考文献：
  名称：

  Synthesis of mer-[RuCl3(DMSO)(bpy)], reactivity and electrochemistry of mer-[RuCl3(DMSO)(bpy)] and mer-[RuCl3(TMSO)(bpy)] complexes

  摘要：

  [H(DMSO)(2)][trans-RuCl4(DMSO)(2)] (1) reacts with 2,2'-bipyridine in ethanol at room temperature resulting in the formation of a major compound, mer-[RuCl3(DMSO)(bpy)] (bpy = 2,2'-bipyridine) 3 and a known minor compound, cis-[RuCl2(DMSO)(4)] (4). The compounds 3 and 4 are formed via an anticipated intermediate mer-[RuCl3(DMSO)(3)] (2). The reaction of 3 and mer-[RuCl3(TMSO)(bpy)] (5) with small molecules like imidazole, carbon monoxide and KSCN yield, mer-[RuCl3(bpy)(im)] center dot 2DMSO (im = imidazole) (6) and cis-[RUCl2(TMSO)(CO)(bpy)] (7), cis-[RuCl2(DMSO)(CO)(bpy)] (8) and K[RuCl3(bpy)(SCN)] (9), respectively. The formations of 3, 6 and 7 have been authenticated by single crystal structure determinations. Compound 6 is formed by the substitution of DMSO or TMSO from 3 and 5, respectively, whereas 7 and 8 are formed by unprecedented one-electron reductions of 5 and 3. The reactions of 3 and 5 with KSCN resulted in the same compound, K[RuCl3(NCS)(bpy)] (9). DFT calculations were performed to distinguish whether the thiocyanate ligand is bound to ruthenium through S or N. In the ruthenium bipyridine systems, the HOMO contains ruthenium d-orbitals and the LUMO is typically pi*-orbitals of the bipyridine ring. Complexes 3, 6 and 7 are redox active in acetone and DMSO solvent showing prominent a reduction peak and corresponding oxidation peak. (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2007.08.016
• 作为产物：
  描述：

  mer-trichlorotris(dimethylsulfoxide)ruthenium(III) 在 2,2'-bipyridine 作用下， 以 甲醇 为溶剂， 生成 mer-[RuCl₃(dimethyl sulfoxide)(2,2'-bipyridyl)]
  参考文献：
  名称：

  钌（III）与二甲亚砜-I的配合物。[Ru2Cl6（DMSO）4]，[RuCl3（DMSO）3]的fac和mer异构体：合成钌（III）配合物的多功能原料

  摘要：

  摘要合成了钌（III）与二甲亚砜（DMSO），[RuCl 3（DMSO）2] 2和[RuCl 3（DMSO）3]的配合物，并通过物理方法对其进行了表征。获得了[RuCl 3（DMSO）3]的fac和mer异构体。fac异构体具有所有S键结合的DMSO，而mer具有S键和O键结合的DMSO分子。根据反应条件和引入配体的性质，使上述三种化合物与S，P，As，N和O供体配体反应，导致部分或完全取代DMSO分子。S，P和As供体配体可完全取代DMSO分子，而N和O供体配体通常可部分取代。制备并表征的新化合物为[RuCl 3 L 2（DMSO）]（其中L = py，CH 3 CN； L 2 = 1,10-菲咯啉，2,2'-联吡啶）和[Ru（acac）（DMSO） 2 Cl 2]。

  DOI：

  10.1016/s0277-5387(00)80404-0

文献信息

• Ruthenium Complexation in an Aluminium Metal-Organic Framework and Its Application in Alcohol Oxidation Catalysis
  作者：Fabian Carson、Santosh Agrawal、Mikaela Gustafsson、Agnieszka Bartoszewicz、Francisca Moraga、Xiaodong Zou、Belén Martín-Matute

  DOI：10.1002/chem.201200885

  日期：2012.11.26

  A ruthenium trichloride complex has been loaded into an aluminium metal–organic framework (MOF), MOF‐253, by post‐synthetic modification to give MOF‐253‐Ru. MOF‐253 contains open bipyridine sites that are available to bind with the ruthenium complex. MOF‐253‐Ru was characterised by elemental analysis, N2 sorption and X‐ray powder diffraction. This is the first time that a Ru complex has been coordinated

  通过合成后修饰将三氯化钌络合物装载到铝金属-有机框架（MOF）-MOF-253中，得到MOF-253-Ru。MOF-253包含开放的联吡啶位点，可用于与钌配合物结合。MOF-253-Ru的特征在于元素分析，N 2吸附和X射线粉末衍射。这是Ru络合物通过合成后的修饰首次与MOF配位并用作多相催化剂。MOF‐253‐Ru催化PhI（OAc）2氧化伯醇和仲醇（包括烯丙醇）在非常温和的反应条件（环境温度至40°C）下作为氧化剂。通过使用低催化剂负载量（0.5 MOl％Ru），可在较短的反应时间（1-3小时）内实现高转化率（高达> 99％）。另外，在室温下获得了对醛的高选择性（> 90％）。MOF‐253‐Ru最多可回收六次，而底物转化率仅适度降低。
• Roles of DMSO-type ruthenium complexes in disaggregation of prion neuropeptide PrP106–126
  作者：Dengsen Zhu、Cong Zhao、Xuesong Wang、Wenji Wang、Baohuai Wang、Weihong Du

  DOI：10.1039/c5ra21523d

  日期：——

  DMSO-type ruthenium complexes with aromatic ligands disaggregate the mature PrP106–126 fibrilsviametal coordination and hydrophobic interaction.

  DMSO型钌配合物与芳香配体通过金属配位和疏水作用使成熟的PrP106-126纤维解聚。