| 18534-71-9

• CAS: 18534-71-9
• 化学式: C₄H₁₂Br₂PdS₂
• 分子量: 390.499
• InChiKey: IAQFRMGPGLATOG-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  3.65
• 重原子数：
  9.0
• 可旋转键数：
  2.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  以 neat (no solvent, solid phase) 为溶剂， 生成 palladium sulfide
  参考文献：
  名称：

  Specific features of the interaction of components in the DMSO−HBr−Pd0 system

  摘要：

  The products of interaction of components in the donor-acceptor electron-transport (DAET) DMSO-HBr system and their complex formation with the metallic palladium surface were studied. H2O and Me2S (main reaction products) and CO, CS2, C2H6, MeBr, H, and CH4 (minor reaction products) were found in the gas phase by mass spectrometry (MS). The samples of metallic palladium treated with the DAET system with a components ratio corresponding to the minimum and maximum rates of metal dissolution were studied by the methods of thermoprogrammed desorption with MS detection (TPD-MS) and XPS. According to the TPD-MS data, two forms of Me2S are present on the metal surface, whereas the XPS method detected two complexes with the molecular compositions (PdBr4S1.26)-Br-11 and (PdBr3.86S1.42)-Br-11 The addition of an aqueous solution of NaOH to the system results in the formation of HCOONa, which indicates that compounds (CH2O, HCOOH) capable of reducing the palladium complexes are present in the DAET system.

  DOI：

  10.1007/bf02496341
• 作为产物：
  描述：

  氢溴酸 、 钯 、 二甲基亚砜 以 neat (no solvent) 为溶剂， 生成
  参考文献：
  名称：

  Specific features of the interaction of components in the DMSO−HBr−Pd0 system

  摘要：

  The products of interaction of components in the donor-acceptor electron-transport (DAET) DMSO-HBr system and their complex formation with the metallic palladium surface were studied. H2O and Me2S (main reaction products) and CO, CS2, C2H6, MeBr, H, and CH4 (minor reaction products) were found in the gas phase by mass spectrometry (MS). The samples of metallic palladium treated with the DAET system with a components ratio corresponding to the minimum and maximum rates of metal dissolution were studied by the methods of thermoprogrammed desorption with MS detection (TPD-MS) and XPS. According to the TPD-MS data, two forms of Me2S are present on the metal surface, whereas the XPS method detected two complexes with the molecular compositions (PdBr4S1.26)-Br-11 and (PdBr3.86S1.42)-Br-11 The addition of an aqueous solution of NaOH to the system results in the formation of HCOONa, which indicates that compounds (CH2O, HCOOH) capable of reducing the palladium complexes are present in the DAET system.

  DOI：

  10.1007/bf02496341

文献信息

• Synthesis, spectroscopic, and structural studies of the methylpalladium(<scp>II</scp>) complexes [{PdMe(SMe₂)X}₂](X = Cl, Br, or I); crystal structure of trans-[{PdMe(SMe₂)(µ-Cl)}₂]
  作者：Peter K. Byers、Allan J. Canty、Lutz M. Engelhardt、Allan H. White

  DOI：10.1039/dt9860001731

  日期：——

  The complexes [PdMe(SMe2)X}2](X = Cl, Br, or I) have been prepared by reaction of trans[Pd(SMe2)2X2] with halide-free methyl-lithium (X = Cl or Br), and reaction of trans-[Pd(SMe2)2Cl2] with methyl-lithium containing lithium iodide (X = I) in diethyl ether at –60 to –15 °C under nitrogen. Other synthetic routes to the bromo- and iodo-complexes are also described. The crystal structure of the chloro-complex

  配合物[PdMe（SMe 2）X} 2 ]（X = Cl，Br或I）是通过反式[Pd（SMe 2）2 X 2 ]与不含卤化物的甲基锂（X = Cl或Br），然后在氮气下于–60至–15°C的条件下将反式-[Pd（SMe 2）2 Cl 2 ]与含碘化锂的甲基锂（X = I）在乙醚中反应。还描述了溴和碘配合物的其他合成途径。氯配合物[PdMe（SMe 2）（µ-Cl）} 2 ]的晶体结构已通过单晶X确定于295 K处进行X射线衍射，并通过最小二乘法将其对1 914个独立的“观察到的”反射进行精制，R = 0.025 [空间组P 2 1 / n，a = 10.792（4），b = 7.373（2），c = 9.131（5）Å，β= 109.03（3）°，Z = 2]。中心对称二聚体分子具有桥连的氯基和正方形平面几何形状的反式立体化学钯（II）。1 H Nmr和远红外光谱以及分子量测定与溴和碘配合物的相似结构一致。
• A chiral [2]catenane self-assembled from meso-macrocycles of palladium(ii)
  作者：Tara J. Burchell、Dana J. Eisler、Richard J. Puddephatt

  DOI：10.1039/b413258k

  日期：——

  icro-S-LL)] but the resulting [2]catenane is chiral as a direct result of the catenation step. This is the first time that this form of chiral [2]catenane has been observed. The enantiomers of the [2]catenane further self-assemble in the crystalline form, through secondary intermolecular PdX bonding, to form a racemic infinite supramolecular polymer of [2]catenanes.

  反式[PdX2（SMe2）2]（X = Cl或Br）与手性配体LL = 1,1'-联萘-2,2'-（NHC（= O）-3-C5H4N）2的反应[2] catenane配合物反式-[（PdX2）2（micro-LL）2} 2]，由反式-PdX2和LL的4个单元自组装而成。通过在组成的大环之间形成多个氢键（4 x NHClPd，2 x NHO双键C）来促进串联。如果配体LL是外消旋的，则每个大环反式[[（PdX2）2（micro-LL）2]以内消旋形式形成-[（PdX2）2（micro-R-LL）（micro-S-LL） ]，但是作为[2]邻烷的手性是串联步骤的直接结果。这是首次观察到这种形式的手性[2]环戊烷。[2]环戊烷的对映体通过次级分子间PdX键进一步以结晶形式自组装，
• Mann, F. G.; Purdie, D., Journal of the Chemical Society
  作者：Mann, F. G.、Purdie, D.

  DOI：——

  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Pd: MVol.2, 126, page 409 - 411
  作者：

  DOI：——

  日期：——
• Kokoreva, S. G.; Nifontova, G. A.; Korableva, L. G., Russian Journal of Inorganic Chemistry, 1995, vol. 40, p. 1270 - 1274
  作者：Kokoreva, S. G.、Nifontova, G. A.、Korableva, L. G.、Sikorenko, Yu. B.、Lavrent'ev, I. P.

  DOI：——

  日期：——