(12-methyl-12-nitro-4,7-dioxa-1,10-diazacyclotridecane)copper(II) tetrachlorozincate | 866529-49-9

• 英文名称: (12-methyl-12-nitro-4,7-dioxa-1,10-diazacyclotridecane)copper(II) tetrachlorozincate
• CAS: 866529-49-9
• 化学式: C₁₀H₂₁CuN₃O₄*Cl₄Zn
• 分子量: 518.042
• InChiKey: TTXFQYQLQXEENS-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1,8-二氨基-3,6-二氧杂辛烷 在 Et₃N 作用下， 以 甲醇 、 水 、 丙酮 为溶剂， 生成 (12-methyl-12-nitro-4,7-dioxa-1,10-diazacyclotridecane)copper(II) tetrachlorozincate
  参考文献：
  名称：

  Macrocyclic dioxadiaza from the reaction of the (1,8-diamino-3,6-dioxaoctane)copper(II) cation with formaldehyde and the carbon acids nitroethane or diethylmalonate

  摘要：

  New square-planar copper(II) complexes of 13-membered dioxa diaza macrocyclic ligands, (12-methyl-12-nitro-4,7-dioxa-1,10-diazacyclotridecane)copper(II), [Cu(L-1)](2+); and (12,12-dicarboxyethyl-4,7-dioxa-1,10-diazacyclotridecane)copper(II), [Cu(L-2)](2+); with perchlorate, hexafluorophosphate and tetrachlorozincate as counter ions have been prepared from the one-pot template condensation reaction of formaldehyde and 1,8-diamino-3,6-dioxaoctane with the carbon acids nitroalkane or diethylmalonate in the presence of the copper(II) ion. Elemental analyses, FTIR, UV-Vis, conductometric, cyclic voltametry and magnetic measurements have been used to, characterize the copper(II) complexes of these dioxa-diaza macrocycles. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2005.03.060