(PEt3)2Ni[o-(SiMe2)2-C2B10H10] | 219584-52-8

• 英文名称: (PEt3)2Ni[o-(SiMe2)2-C2B10H10]
• CAS: 219584-52-8
• 化学式: C₁₈H₅₂B₁₀NiP₂Si₂
• 分子量: 553.529
• InChiKey: UPGCZVJHHWDMMN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  1,1-二苯乙烯 、 (PEt3)2Ni[o-(SiMe2)2-C2B10H10] 以 甲苯 为溶剂， 以74%的产率得到
  参考文献：
  名称：

  Stable bis(silyl)nickel complexes with o-carboranyl unit: a facile double silylation of alkynes and alkenes

  摘要：

  邻双(二甲基甲硅烷基)碳硼烷与 Ni(PEt3)4 在戊烷中反应，得到反应中间体[o-(SiMe2)2C2B10H10]Ni(PEt3)2 2；报道了 2 催化的炔烃的简单双硅烷化。

  DOI：

  10.1039/a806457a
• 作为产物：
  描述：

  1,2-bis(dimethylsilyl)-o-carborane 、 tetrakis(triethylphosphine)nickel(0) 以 正戊烷 为溶剂， 以86%的产率得到(PEt3)2Ni[o-(SiMe2)2-C2B10H10]
  参考文献：
  名称：

  Stable bis(silyl)nickel complexes with o-carboranyl unit: a facile double silylation of alkynes and alkenes

  摘要：

  邻双(二甲基甲硅烷基)碳硼烷与 Ni(PEt3)4 在戊烷中反应，得到反应中间体[o-(SiMe2)2C2B10H10]Ni(PEt3)2 2；报道了 2 催化的炔烃的简单双硅烷化。

  DOI：

  10.1039/a806457a
• 作为试剂：
  描述：

  1,2-bis(dimethylsilyl)-o-carborane 、 丙腈 在 (PEt3)2Ni[o-(SiMe2)2-C2B10H10] 作用下， 以 甲苯 为溶剂， 以66%的产率得到
  参考文献：
  名称：

  腈与1,2-双（二甲基甲硅烷基）碳环的新型镍催化反应

  摘要：

  1,2-双（二甲基甲硅烷基）碳烷（1）与丙腈的镍催化反应得到N-甲硅烷基烯胺。没有α-H的腈（如异丁腈，苄腈，对甲苯腈和1-氰基萘）的脱氢双甲硅烷基化反应生成六元环亚胺。相反，在相同反应条件下1与9-蒽碳腈的反应得到五元的N，N-双（甲硅烷基）胺。有趣的是，1与具有α-氢的腈如苄基氰，二苯基乙腈和氢肉桂腈的反应提供了N，N-双（甲硅烷基）烯胺。

  DOI：

  10.1021/om0008629

文献信息

• A Bis(silyl)nickel Complex Containing an <i>o</i>-Carboranylene and Its Application in Facile Double Silylation of Alkynes and Alkenes
  作者：Youngjin Kang、Junghyun Lee、Young Kun Kong、Sang Ook Kang、Jaejung Ko

  DOI：10.1021/om990915q

  日期：2000.5.1

  The reaction of 1,2-bis(dimethylsilyl)carborane (1) with Ni(PEt3)(4) yielded the cyclic bis-(silyl)nickel complex (2). 2 was found to be a good catalyst for the double silylation reaction of alkynes and alkenes. Thus, the reaction of 1 with RC=CR' in the presence of a catalytic amount of 2 afforded the six-membered disilylene ring compounds o-B10H10C2(SiMe2)(2)(RC=CR') (R = R'= Ph (3); R = Ph, R'= H (4); R = R'= Pt (5); R = Ph, R'= Me (6); R = R'= Me (7)). In contrast, the reaction of 1-phenyl-2-(trimethylsilyl)acetylene with 1 in the presence of a catalytic amount of 2 afforded the six-membered disilylene ring compound (9) and the five-membered disilylene ring compound (10). The stoichiometric reaction of 2 with an active alkyne such as dimethyl acetylenedicarboxylate gave the six-membered disilylene ring compound (11). The intermedate 2 also was found to be a good catalyst for the double silylation of some alkenes. Thus, the reaction of 1 with 4-vinylanisole in the presence of a catalytic amount of 2 afforded the five-membered disilylene ring compound (15). However, treatment of 1 with 1,1-diphenylethylene under the same reaction conditions yielded a different type of five-membered disilylene ring compound (17). The reaction of 1 with 2,3-dimethylbutadiene in the presence of the nickel catalyst also was studied. The crystal structures of 2, 9, and 14 are described.