| 133829-40-0

• CAS: 133829-40-0
• 化学式: C₁₈H₁₁F₃O₁₁Os₃Te
• 分子量: 1158.47
• InChiKey: HMWZUZMAQMSSNM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  以 环己烷 为溶剂， 生成
  参考文献：
  名称：

  Room-temperature activation of aliphatic C–H bonds in cyclohexane and pentane by the system [Os₃(CO)₁₁(NCMe)]–Te(CF₃)₂: X-ray crystal structure of [Os₃(CO)₁₁{Te(C₆H₁₁)₂}]

  摘要：

  The reaction of [OS3(CO)11(NCMe)] with bis(trifluoromethyl)telluride, Te(CF3)2, in cyclohexane yields the cluster [OS3(CO)11{Te(C6H11)2}] 2 in which the CF3 substituents at the tellurium are replaced by two cyclohexyl substituents; the isolation of the intermediate [OS3(CO)11{Te(CF3)(C6H11)} 1 in the dark reveals that the first C-H activation of the cyclohexane is a thermal process, whereas the second C-H activation requires sunlight.

  DOI：

  10.1039/c39910000447
• 作为产物：
  描述：

  undecacarbonyl(acetonitrile)triosmium 、 环己烷 、 bis(trifluoromethyl)tellurium 以 环己烷 为溶剂， 以92%的产率得到
  参考文献：
  名称：

  Room-temperature activation of aliphatic C–H bonds in cyclohexane and pentane by the system [Os₃(CO)₁₁(NCMe)]–Te(CF₃)₂: X-ray crystal structure of [Os₃(CO)₁₁{Te(C₆H₁₁)₂}]

  摘要：

  The reaction of [OS3(CO)11(NCMe)] with bis(trifluoromethyl)telluride, Te(CF3)2, in cyclohexane yields the cluster [OS3(CO)11{Te(C6H11)2}] 2 in which the CF3 substituents at the tellurium are replaced by two cyclohexyl substituents; the isolation of the intermediate [OS3(CO)11{Te(CF3)(C6H11)} 1 in the dark reveals that the first C-H activation of the cyclohexane is a thermal process, whereas the second C-H activation requires sunlight.

  DOI：

  10.1039/c39910000447