(octaethylporphyrinato dianion)Ru(NO)(O-i-C5H11) | 246162-72-1

• 英文名称: (octaethylporphyrinato dianion)Ru(NO)(O-i-C5H11)
• 英文别名: (octaethylporphyrinato)Ru(NO)(O-isoamyl)；(OEP)Ru(NO)(i-O-C5H11)
• CAS: 246162-72-1
• 化学式: C₄₁H₅₅N₅O₂Ru
• 分子量: 750.99
• InChiKey: OBQRUJPOWNGLQK-SBYLDBAISA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  N-t-butyl-N-nitrosohydroxylamine 、 (octaethylporphyrinato dianion)Ru(NO)(O-i-C5H11) 以 二氯甲烷 为溶剂， 反应 12.0h， 以61%的产率得到
  参考文献：
  名称：

  Unusual monodentate binding of a C-NONOate ligand in the nitrosyl complex (OEP)Ru(NO)(η1-ONN(t-Bu)O)

  摘要：

  The recent discovery of the C-NONOate moiety ([X{N2O2}](-); diazeniumdiolate) as a new class of siderophore functional group necessitates further examination of its coordination chemistry. The bidentate eta(2)-O,O binding mode of the C-NONOate moiety is well-established. We have synthesized and characterized, by X-ray crystallography, the first monodentate eta(1)-O binding mode of a C-NONOate group to any metal, namely that of (OEP)Ru(NO)(eta(1)-ONN(t-Bu)O). The compound exhibits an irreversible first oxidation in CH2Cl2 at a Pt electrode. Protonation with triflic acid results in the formation of N2O, presumably from the direct protonation of the C-NONOate ligand.

  DOI：

  10.1016/j.ica.2020.119567
• 作为产物：
  描述：

  2,3,7,8,12,13,17,18-octaethyl-21H,23H-porphine ruthenium(II) carbonyl 、 亚硝酸异戊酯 以 not given 为溶剂， 生成 (octaethylporphyrinato dianion)Ru(NO)(O-i-C5H11)
  参考文献：
  名称：

  Photo-induced metastable linkage isomers of ruthenium nitrosyl porphyrins

  摘要：

  红外光谱结果结合早期关于铁和钌亚硝基配合物的晶体学和光谱学证据表明，在低温辐照下，亚硝基金属卟啉（OEP）Ru(NO)L（L = O-i-C5H11，SCH2CF3）形成了不稳定的η1-O和η2-NO连接异构体；这些新化合物在低温下稳定，但在升温时会回复到基态。

  DOI：

  10.1039/a905285b

文献信息

• Lee, Jonghyuk; Yi, Geun-Bae; Khan, Masood A., Inorganic Chemistry, 1999, vol. 38, # 20, p. 4578 - 4584
  作者：Lee, Jonghyuk、Yi, Geun-Bae、Khan, Masood A.、Richter-Addo, George B.

  DOI：——

  日期：——
• Synthesis, characterization, and redox behavior of six-coordinate (por)Ru(NO)Cl compounds (por=porphyrinato dianion)
  作者：Nan Xu、Jonghyuk Lee、Douglas R. Powell、George B. Richter-Addo

  DOI：10.1016/j.ica.2004.06.031

  日期：2005.6

  A new high-yield preparative route to (por)Ru(NO)Cl compounds (por=porphyrinato dianion) from reactions of (por)Ru(NO)(alkoxide) precursors with boron trichloride is reported. These ruthenium nitrosyl chloride complexes are known to be useful precursors to (por)Ru(NO)-containing derivatives. The crystal structure of (OEP)Ru(NO)Cl (OEP = octaethylporphyrinato dianion) shows that the Ru-N-O linkage is linear. The redox behavior of the (por)Ru(NO)Cl compounds has been determined by cyclic voltammetry. Analysis of the data reveals that the first oxidation of the (por)Ru(NO)Cl compounds is porphyrin-ring centered. (c) 2004 Elsevier B.V. All rights reserved.