(η4-1,5-cyclooctadiene)(1-diphenylphosphanyl-2-diphenylphosphanylmethyl-8-(trimethoxysilyl)octane)rhodium(I) hexafluoroantimonate(V) | 412915-18-5

• 英文名称: (η4-1,5-cyclooctadiene)(1-diphenylphosphanyl-2-diphenylphosphanylmethyl-8-(trimethoxysilyl)octane)rhodium(I) hexafluoroantimonate(V)
• CAS: 412915-18-5
• 化学式: C₄₄H₅₈O₃P₂RhSi*F₆Sb
• 分子量: 1063.62
• InChiKey: LGVZWAYQEZMZJI-UZHIGMTKSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  (η4-1,5-cyclooctadiene)(1-diphenylphosphanyl-2-diphenylphosphanylmethyl-8-(trimethoxysilyl)octane)rhodium(I) hexafluoroantimonate(V) 、 水 在 二乙酸二丁基锡 作用下， 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  Supported organometallic complexes. Part 27: novel sol–gel processed rhodium(I) complexes: synthesis, characterization, and catalytic reactions in interphases

  摘要：

  A novel T-silyl functionalized cationic (COD)(dppp)rhodium(l) complex was sol-gel processed with various amounts of the co-condensing agents MeSi(OMe)(2)(CH2)(6)(OMe)(2)SiMe and MeSi(OMe)(2)(CH2)(3)(C6H4)(CH2)(3)(OMe)(2)SiMe to give novel stationary phases for 'Chemistry in Interphases'. The polysiloxane matrices and the integrity of the rhodium(I) complex centers were investigated by means of multinuclear solid-state NMR (C-13, Si-29, P-31) and EXAFS spectroscopics. Dynamic NMR measurements show an increasing mobility of the matrix and the reactive centers with a higher amount of the co-condensing component. The accessibility of the anchored rhodium(I) centers was scrutinized by the metal catalyzed hydrogenation of 1-hexene. All applied xerogels show remarkable activities and selectivities. An enhancement of the activities is achieved when polar solvents are used. SEM micrographs reveal the morphology of the hybrid materials and energy dispersive X-ray spectroscopy (EDX) suggests that the distribution of the elements is in satisfying agreement with the applied composition. (C) 2002 Published by Elsevier Science B.V.

  DOI：

  10.1016/s0020-1693(01)00675-2
• 作为产物：
  描述：

  silver hexafluoroantimonate 、 di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium 、 1-diphenylphosphanyl-2-diphenylphosphanylmethyl-8-(trimethoxysilyl)octane 以 四氢呋喃 为溶剂， 以88%的产率得到(η4-1,5-cyclooctadiene)(1-diphenylphosphanyl-2-diphenylphosphanylmethyl-8-(trimethoxysilyl)octane)rhodium(I) hexafluoroantimonate(V)
  参考文献：
  名称：

  Supported organometallic complexes. Part 27: novel sol–gel processed rhodium(I) complexes: synthesis, characterization, and catalytic reactions in interphases

  摘要：

  A novel T-silyl functionalized cationic (COD)(dppp)rhodium(l) complex was sol-gel processed with various amounts of the co-condensing agents MeSi(OMe)(2)(CH2)(6)(OMe)(2)SiMe and MeSi(OMe)(2)(CH2)(3)(C6H4)(CH2)(3)(OMe)(2)SiMe to give novel stationary phases for 'Chemistry in Interphases'. The polysiloxane matrices and the integrity of the rhodium(I) complex centers were investigated by means of multinuclear solid-state NMR (C-13, Si-29, P-31) and EXAFS spectroscopics. Dynamic NMR measurements show an increasing mobility of the matrix and the reactive centers with a higher amount of the co-condensing component. The accessibility of the anchored rhodium(I) centers was scrutinized by the metal catalyzed hydrogenation of 1-hexene. All applied xerogels show remarkable activities and selectivities. An enhancement of the activities is achieved when polar solvents are used. SEM micrographs reveal the morphology of the hybrid materials and energy dispersive X-ray spectroscopy (EDX) suggests that the distribution of the elements is in satisfying agreement with the applied composition. (C) 2002 Published by Elsevier Science B.V.

  DOI：

  10.1016/s0020-1693(01)00675-2