trans-[dichloro(1,4,8,12-tetraazacyclopentadecane)ruthenium]PF6 | 733747-36-9

• 英文名称: trans-[dichloro(1,4,8,12-tetraazacyclopentadecane)ruthenium]PF6
• CAS: 733747-36-9
• 化学式: C₁₁H₂₆Cl₂N₄Ru*F₆P
• 分子量: 531.294
• InChiKey: MIFMYNMSLBKPES-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  盐酸 、 trans-[dichloro(1,4,8,12-tetraazacyclopentadecane)ruthenium]PF6 、 氧化亚氮 在 汞 、 锌 作用下， 以 水 为溶剂， 以23%的产率得到trans-[RuCl(NO)(1,4,8,12-tetraazacyclopentadecane)]Cl2
  参考文献：
  名称：

  Nitrosyl ruthenium complex as nitric oxide delivery agent: synthesis, characterization and photochemical properties

  摘要：

  In the present study, we report the synthesis, physical chemistry and photochemical properties of trans-[RuCl([15]aneN(4))NO](2+) in physiological solution. The nitrosyl ruthenium species undergoes one-electron reduction in aqueous solution producing trans[RuCl([15]aneN(4))H2O](+) and nitric oxide (NO). The NO was also obtained with a laser flash-photolysis at 355 nm of trans[RuCl([15]aneN(4))NO](2+) in aqueous solution. The quantum yield for NO release was determined as 0.61+/-0.05 mol einstein(-1) (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2003.10.025
• 作为产物：
  描述：

  ammonium hexafluorophosphate 、 1,4,8,12-四氮杂环十五烷 、 水合三氯化钌 在 氢气 作用下， 以 甲醇 、 水 为溶剂， 以53%的产率得到trans-[dichloro(1,4,8,12-tetraazacyclopentadecane)ruthenium]PF6
  参考文献：
  名称：

  Nitrosyl ruthenium complex as nitric oxide delivery agent: synthesis, characterization and photochemical properties

  摘要：

  In the present study, we report the synthesis, physical chemistry and photochemical properties of trans-[RuCl([15]aneN(4))NO](2+) in physiological solution. The nitrosyl ruthenium species undergoes one-electron reduction in aqueous solution producing trans[RuCl([15]aneN(4))H2O](+) and nitric oxide (NO). The NO was also obtained with a laser flash-photolysis at 355 nm of trans[RuCl([15]aneN(4))NO](2+) in aqueous solution. The quantum yield for NO release was determined as 0.61+/-0.05 mol einstein(-1) (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2003.10.025