Oxygen evolution by water oxidation with polynuclear ruthenium complexes
作者:Ramasamy Ramaraj、Akira Kira、Masao Kaneko
DOI:10.1039/f19878301539
日期:——
of a trinuclear rutheniumcomplex (Ruthenium red) have been carried out. Di- and tri-nuclear rutheniumcomplexes were adsorbed onto clay and ion-exchangeresin and were then used as homogeneous and heterogeneous (clay-and resin-adsorbed) catalysts for wateroxidation to evolve oxygen. The gas-chromatographic and mass-spectral data clearly show that oxygen evolved by wateroxidation is catalysed by