chloro[4-((4'-(n-decyloxy)benzoyl)oxy)phenyl isonitrile]gold | 854053-05-7

• 英文名称: chloro[4-((4'-(n-decyloxy)benzoyl)oxy)phenyl isonitrile]gold
• CAS: 854053-05-7
• 化学式: C₂₄H₂₉AuClNO₃
• 分子量: 611.919
• InChiKey: XOLINSXBYLNETN-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  丙醇 、 chloro[4-((4'-(n-decyloxy)benzoyl)oxy)phenyl isonitrile]gold 以 丙醇 为溶剂， 以85%的产率得到chloro[(propoxy)((4-((4'-(n-decyloxy)benzoyl)oxy)phenyl)amino)carbene]gold
  参考文献：
  名称：

  Syntheses and Mesomorphic Properties of Gold(I)−Carbene Complexes

  摘要：

  The liquid-crystalline gold(I)-carbene complexes ClAu=C(YCmH2m+1)(NHC6H4CO2C6H4OCnH2n+1), Y = O and NH, have been prepared by reactions of gold(I)-isonitrile complexes [ClAu{CNC6H4CO2C6H4OCnH2n+1}] with alcohols and amines, respectively. The gold(I)-(alkoxy)(amino)carbene complexes show stable enantiotropic smectic A phases over the range of around 15 degrees C. The partial double-bond character of the C-N bond in the carbene complex gives rise to two geometrical isomers (E:Z = ca. 3:1). Their molecular structures were spectroscopically characterized, and the E-isomer was confirmed by an X-ray structural analysis. The phase behaviors of E- and Z-isomers which were isolated by repeated recrystallization from CHCl3/Et(2)O or CH2Cl2/C6H14 were examined. In the gold(I)-diaminocarbene complexes, a novel dinuclear gold-carbene complex, [ClAu{C(NHC6H4CO2C6H4OCnH2n+1)}](NCH3CmH2mNCH3)[ClAu{C(NHC6H4CO2C6H4OCnH2n+1)}], was synthesized by the reaction with a secondary diamine. This dinuclear complex generated a smectic mesophase although it decomposed at temperatures below its clearing temperature.

  DOI：

  10.1021/om9606202
• 作为产物：
  描述：

  (tetrahydrothiophene)gold(I) chloride 、 (4-Isocyanophenyl) 4-decoxybenzoate 以 二氯甲烷 为溶剂， 以90%的产率得到chloro[4-((4'-(n-decyloxy)benzoyl)oxy)phenyl isonitrile]gold
  参考文献：
  名称：

  有机片段对一系列有机金（I）异氰化物配合物的介晶性质的影响。[Au（CCC 5 H 4 N）（CNC 6 H 4 O（O）CC 6 H 4 OC 10 H 21）的X射线晶体结构]

  摘要：

  制备棒状有机金（I）配合物[AuR（CNC 6 H 4 O（O）CC 6 H 4 OC 10 H 21 - p）]，并研究其液晶行为。取决于R的性质，合成方法是不同的。因此，对于R =取代的炔基配体，分两个步骤制备新化合物：（i）[AuCl（tht）]（tht =四氢噻吩）与R'CCH（R'= C 5 H 4 N，C 6 H 4 CN，C 6 H 4 CCC 5 H 4 N）在NaOAc的存在下产生不溶性[Au（CCR'）] n; （ii）后者与异腈CNC 6 H 4 O（O）CC 6 H 4 OC 10 H 21 - p的反应。对于R =氟化芳基，通过从化合物[AuR（ tht）]（R = C 5 F 4 N，C 6 F 4 C 5 H 4 N，C 6 F 5）与异腈。此外，意外的离子衍生物[Au（CCC 5 H 4 NC 10 H 21）2 ] [Au（CCC第五名ħ 4 N）2 ]被形成了[PPH之间的反应4

  DOI：

  10.1016/j.jorganchem.2005.02.043