| 897401-39-7

• CAS: 897401-39-7
• 化学式: C₃₁H₄₄ClP₂Rh
• 分子量: 616.996
• InChiKey: FXVDUYHAGHYGQT-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [(C10H5(CH2P(i-Pr)2)2)Rh]2(η1-N2) 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  Metal-Controlled Reactivity of a Pincer-type, σ-Coordinated Naphthyl Radical Anion

  摘要：

  Reduction of the new, naphthalene-based pincer complex [(C10H5(CH2PiPr2)2)Rh(eta1-N2)] with potassium metal gave the corresponding sigma-coordinated naphthyl radical anion complex, with a ring-centered radical and no change in the formal metal oxidation state. This paramagnetic complex can be reoxidized to the diamagnetic one with [Cp2Fe][BF4], the structural integrity being retained. Unexpectedly, treatment of a THF solution of the reduced complex with water leads to the immediate evolution of dihydrogen, with reoxidation to the starting complex. This is in striking contrast with the well-known reactivity of the naphthide radical anion, which undergoes ring protonation by water to form 1,4-dihydronaphthalene and naphthalene in a 1:1 ratio.

  DOI：

  10.1021/ja0615066