bis(2,6-xylyl-diazadiene)-bis-chloro-ruthenium | 90742-41-9

• 英文名称: bis(2,6-xylyl-diazadiene)-bis-chloro-ruthenium
• CAS: 90742-41-9
• 化学式: C₃₆H₄₀Cl₂N₄Ru
• 分子量: 700.716
• InChiKey: XJTWGTAXWPURHH-ZBZXFALGSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  bis(2,6-xylyl-diazadiene)-bis-chloro-ruthenium 在 potassium 作用下， 以 四氢呋喃 为溶剂， 生成 bis(2,6-xylyldiazadiene)ruthenium
  参考文献：
  名称：

  Rosenberger, Volker; Dieck, Heindirk tom, Chemische Berichte, 1990, vol. 123, p. 83 - 86

  摘要：

  DOI：
• 作为产物：
  描述：

  trans-{RuCl2(C6H5CN)4} 、 N-[(1E,2E)-2-(2,6-dimethylphenyl)ethylidene]-2,6-dimethylphenylamine 以 二乙二醇 为溶剂， 以73%的产率得到
  参考文献：
  名称：

  Dieck, Heindirk Tom; Kollvitz, Wolfgang; Kleinwächter, Ingo, Inorganic Chemistry, 1984, vol. 23, # 17, p. 2685 - 2691

  摘要：

  DOI：

文献信息

• Diazadien-Komplexe des Rutheniums
  作者：Volker Rosenberger、Gert Fendesak、Heindirk tom Dieck

  DOI：10.1016/0022-328x(91)83049-a

  日期：1991.7

  Bis(diazadiene)dichlororuthenium (R-DAD)2RuCl2 (1) (R-DAD = RN = CHCH = NR with R = 2,6-xylyl) reacts with 2 mol of potassium in tetrahydrofuran to give the unsaturated (R-DAD)2Ru (2) and its isomer (3), in which one of the o-methyl groups of R is metalated. The hydrogen is transferred to the neighbouring imine carbon of the DAD to form an iminaminato type ligand, N = CHCH2N. Reduction of 1 in the presence of hydrogen or addition of hydrogen to 2 affords a hydride (4) with one Ru-H bond and one iminaminato ligand. The addition is reversible and at higher temperatures 2 and 3 are formed again. Reduction of 1 with 3-4 mol of potassium gives a reduction product of composition K2[Ru(R-DAD)2] (5) and a deprotonation product (6). A single crystal X-ray diffraction study was performed for 6. The coordination of the Ru0 center is intermediate between square pyramidal and trigonal bipyramidal with four imine N donors and a carbon ligand, resulting from the o-methyl metalation of one R-DAD. [K(tmeda)2]+ is the counterion. The potassium ion being unsufficiently saturated by the tmeda ligands has further contacts with some of the carbon atoms of the o-methyl metalated aromatic ring.