[η5-pentamethylcyclopentadienyl-[1,2-dicarba-closo-dodecaborane(12)-diselenolato]iridium][Co2(CO)5] | 847660-18-8

• 英文名称: [η5-pentamethylcyclopentadienyl-[1,2-dicarba-closo-dodecaborane(12)-diselenolato]iridium][Co2(CO)5]
• CAS: 847660-18-8
• 化学式: C₁₇H₂₅B₁₀Co₂IrO₅Se₂
• 分子量: 885.619
• InChiKey: BOBCNIHMMCZTGY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  dicobalt octacarbonyl 、 η5-pentamethylcyclopentadienyl-[1,2-dicarba-closo-dodecaborane(12)-diselenolato]iridium 在 (CH₃)3NO 作用下， 以 甲苯 为溶剂， 生成 [η5-pentamethylcyclopentadienyl-[1,2-dicarba-closo-dodecaborane(12)-diselenolato]iridium][Co2(CO)5]
  参考文献：
  名称：

  Synthesis and Structure of Heterometallic Clusters (IrCo₂, IrFe) Containing Bridging 1,2-Dicarba-closo-dodecaborane-1,2-dichalocogenolato Ligands

  摘要：

  The 16-electron half-sandwich iridium complexes [Cp*Ir{E2C2(B10H10)}] [E = S (1a), Se (1b)] (Cp* = eta(5)-C5Me5) [Cp*Ir[E2C2(B10H10)] = eta(5)-pentamethylcyclopentadienyl-[1,2-dicarbacloso-dodecaborane(12)-dichalcogenolato]iridium] reacted with Co-2(CO)(8) in toluene solution to afford the trinuclear clusters [Cp*Ir{E2C2(B10H10)}]{Co-2(CO)(5)} [E = S (2a), Se (2b)] and mononuclear complexes [Cp*Ir(CO){E2C2(B10H10)}] [E = S (3a), Se (3b)] as byproducts. Compounds 2a and 2b contain closed IrCo2 triangle geometry with one Co-Co and two Ir-Co bonds. The dinuclear IrFe complexes [Cp*Ir{E2C2(B10H10)}]{Fe(CO)(3)} [E = S (4a), Se (4b)] were obtained from the reactions of 1a and 1b with Fe(CO)5 in the presence of Me3NO. The molecular structures of 2a, 2b, and 4b have been determined by X-ray crystallography.

  DOI：

  10.1021/om049185z