| 135584-40-6

• CAS: 135584-40-6
• 化学式: C₄₆H₄₂O₄P₂Pt
• 分子量: 915.865
• InChiKey: XPUGRQOKIOXIEM-ZGOHZKFSSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  乙烯双(三苯基磷)铂 、 dimethyl 3-vinylcyclobutene-1,2-dicarboxylate 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  Isomerization of a vinylcyclobutene to a cyclohexadiene: a nickel(I) promoted rearrangement

  摘要：

  The nickel-promoted isomerization of a 3-vinylcyclobutene to the corresponding 1,4-cyclohexadiene was studied by using (PPh3)2Ni(C2H4) as the nickel source. Through the use of chemical and electrochemical experiments, it was determined that nickel(I) and not nickel(0) promotes this isomerization reaction at room temperature. The corresponding platinum-vinylcyclobutene complex 4 has been characterized by a single-crystal X-ray diffraction study: C46H42O4P2Pt, monoclinic, P2(1)/n, with a = 10.774 (1) angstrom, b = 20.281 (4) angstrom, c = 18.297 (2) angstrom, beta = 97.37 (1)-degrees, Z = 4, R(F) = 0.0378, and R(w)(F) = 0.0371.

  DOI：

  10.1021/om00054a072