| 145721-68-2

• CAS: 145721-68-2
• 化学式: C₁₈H₂₂Co₂O₆S₂
• 分子量: 516.487
• InChiKey: FKBPGUCLDQSGHO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 双二苯基膦甲烷 以 苯 为溶剂， 以86%的产率得到{Co2(μ-nBuSCH2CCCH2S-nBu)(μ-bis(diphenylphosphino)methane)(CO)4}
  参考文献：
  名称：

  The synthesis of dimetallic thioalkyne complexes of cobalt and molybdenum

  摘要：

  Treatment of [Co2(mu-HOCR2'C=CCR2'OH)(CO)6] With an excess of RSH in the presence of HBF4.OEt2 affords [Co2(mu-RSCR2'C=CCR2'SR)(CO)6] (R'= H, R = Et, (n)Bu, (t)Bu, Ph, Bz; R'= Me, R = Et), which undergo substitution with bis(diphenylphosphino)methane (dppm) to give [Co2(mu-RSCR2'C=CCR2'SR)(mu-dppm)(CO)4]. Similar treatment of [MoCo(mu-HOCH2C=CCH2OH)(CO)5Cp] and [Mo2(mu-HOCH2C=CCH2OH)(CO)4Cp2] with EtSH gives [MoCo(mu-EtSCH2C=CCH2SEt)(CO)5-Cp] and [Mo2(mu-EtSCH2C=CCH2SEt)(CO)4Cp2], respectively. Reaction of [Co2(mu-HOCH2C=CCH2-OH)(CO)6] with a small excess of RSH (R=Et or Ph), ca. two equivalents, affords [Co2(mu-HOCH2C=CCH2-SR)(CO)6], while reaction with only one equivalent of EtSH additionally gives an ether-bridged system containing two hexacarbonyldicobalt units, [Co2(CO)6(HOCH2C= CCH2OCH2C=CCH2SEt)-Co2(CO)6]. Treatment of [Co2(mu-HOCH2C=CCH2SEt)(CO)6] with half an equivalent of HBF4.OEt2 affords [Co2(CO)6(EtSCH2C=CCH2OCH2C=CCH2SEt)Co2(CO)6]. Attempted preparation of mixed thioether complexes results in a mixture of products, and a mechanism is proposed for thioether scrambling. The IR, NMR and mass spectra of the new compounds are reported and discussed.

  DOI：

  10.1016/0022-328x(92)80229-q
• 作为产物：
  描述：

  2-butyne-1,4-diol-hexacarbonyldicobalt 、 丁硫醇 在 四氟硼酸-二乙醚络合物 、 碳酸氢钠 作用下， 以 二氯甲烷 为溶剂， 以53%的产率得到
  参考文献：
  名称：

  The synthesis of dimetallic thioalkyne complexes of cobalt and molybdenum

  摘要：

  Treatment of [Co2(mu-HOCR2'C=CCR2'OH)(CO)6] With an excess of RSH in the presence of HBF4.OEt2 affords [Co2(mu-RSCR2'C=CCR2'SR)(CO)6] (R'= H, R = Et, (n)Bu, (t)Bu, Ph, Bz; R'= Me, R = Et), which undergo substitution with bis(diphenylphosphino)methane (dppm) to give [Co2(mu-RSCR2'C=CCR2'SR)(mu-dppm)(CO)4]. Similar treatment of [MoCo(mu-HOCH2C=CCH2OH)(CO)5Cp] and [Mo2(mu-HOCH2C=CCH2OH)(CO)4Cp2] with EtSH gives [MoCo(mu-EtSCH2C=CCH2SEt)(CO)5-Cp] and [Mo2(mu-EtSCH2C=CCH2SEt)(CO)4Cp2], respectively. Reaction of [Co2(mu-HOCH2C=CCH2-OH)(CO)6] with a small excess of RSH (R=Et or Ph), ca. two equivalents, affords [Co2(mu-HOCH2C=CCH2-SR)(CO)6], while reaction with only one equivalent of EtSH additionally gives an ether-bridged system containing two hexacarbonyldicobalt units, [Co2(CO)6(HOCH2C= CCH2OCH2C=CCH2SEt)-Co2(CO)6]. Treatment of [Co2(mu-HOCH2C=CCH2SEt)(CO)6] with half an equivalent of HBF4.OEt2 affords [Co2(CO)6(EtSCH2C=CCH2OCH2C=CCH2SEt)Co2(CO)6]. Attempted preparation of mixed thioether complexes results in a mixture of products, and a mechanism is proposed for thioether scrambling. The IR, NMR and mass spectra of the new compounds are reported and discussed.

  DOI：

  10.1016/0022-328x(92)80229-q