| 362664-09-3

• CAS: 362664-09-3
• 化学式: C₇H₁₀N*C₂₂H₃₄F₇Ti₂
• 分子量: 635.424
• InChiKey: TZIUEZLMLVRNJP-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  四氢呋喃 、 、 lanthanum(lll) triflate 以 四氢呋喃 为溶剂， 以54%的产率得到
  参考文献：
  名称：

  Synthesis and the crystal structures of a monoanionic tetrafluorodentate ligand and its complex with lanthanum ion

  摘要：

  New organotitanium fluorides [Hdmpy](+)[(C5Me4R)(2)Ti2F7](-) (R = Me 4, Et 5, dmpy = 2,6-dimethylpyridine, lutidine) have been prepared from (C5Me4R)TiF3 and 2,6-dimethyIpyridine . (HF)(2). The compounds 4 and 5 react with La(CF3SO3)(3) to give [La{(C5Me4R)(2)Ti2F7}(3)] (R = Me 6, Et 7) containing the [(C5Me4R)(2)Ti2F7](-) anion as a tetrafluorodentate ligand in the crystal structures of 4 and 7. The cation-anion pair is connected by a hydrogen bond in 4 and the all-fluorine environment of 12 fluorine atoms coordinated to a lanthanum ion is found in 7. (C) 2001 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(01)00789-6
• 作为产物：
  描述：

  2,6-二甲基吡啶 、 1-ethyl-2,3,4,5-tetramethylcyclopenta-1,3-diene;trifluorotitanium(1+) 、 2,6-dimethylpyridine-bishydrofluoride 以 甲苯 为溶剂， 以92%的产率得到
  参考文献：
  名称：

  Synthesis and the crystal structures of a monoanionic tetrafluorodentate ligand and its complex with lanthanum ion

  摘要：

  New organotitanium fluorides [Hdmpy](+)[(C5Me4R)(2)Ti2F7](-) (R = Me 4, Et 5, dmpy = 2,6-dimethylpyridine, lutidine) have been prepared from (C5Me4R)TiF3 and 2,6-dimethyIpyridine . (HF)(2). The compounds 4 and 5 react with La(CF3SO3)(3) to give [La{(C5Me4R)(2)Ti2F7}(3)] (R = Me 6, Et 7) containing the [(C5Me4R)(2)Ti2F7](-) anion as a tetrafluorodentate ligand in the crystal structures of 4 and 7. The cation-anion pair is connected by a hydrogen bond in 4 and the all-fluorine environment of 12 fluorine atoms coordinated to a lanthanum ion is found in 7. (C) 2001 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(01)00789-6