(2-(di(2-pyridyl)methylene)-1,3-dithiole-3-carboxylic acid-4-carboxylate)chlorotricarbonylrhenium(I) tetrabutylammonium | 1258005-49-0

• 英文名称: (2-(di(2-pyridyl)methylene)-1,3-dithiole-3-carboxylic acid-4-carboxylate)chlorotricarbonylrhenium(I) tetrabutylammonium
• CAS: 1258005-49-0
• 化学式: C₁₆H₃₆N*C₁₉H₉ClN₂O₇ReS₂
• 分子量: 905.55
• InChiKey: XPYTWXQZJOBQHP-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  甲醇 、 manganese(II) perchlorate hexahydrate 、 (2-(di(2-pyridyl)methylene)-1,3-dithiole-3-carboxylic acid-4-carboxylate)chlorotricarbonylrhenium(I) tetrabutylammonium 以 甲醇 、 二氯甲烷 为溶剂， 以20%的产率得到Mn(MeOH)4[(2-(di(2-pyridyl)methylene)-1,3-dithiole-3-carboxylic acid-4-carboxylate)chlorotricarbonylrhenium(I)]2*2CH3OH
  参考文献：
  名称：

  Syntheses, structures, and properties of tricarbonyl rhenium(I) heteronuclear complexes with the multidentate bridging ligand containing bis(2-pyridine) and carboxylic acid

  摘要：

  By deprotonation reaction of the rhenium(I) tricarbonyl complex, ClRe(CO)(3)(H(2)bpydt) (2, H(2)dpydt = 2(di(2-pyridyl) methylene)-1,3-dithiole-4,5-dicarboxylic acid, our previous work in J. Organomet. Chem. 694 (2009) 763), complex 3, [Bu4N][ClRe(CO)(3)(Hbpydt)], is synthesized and characterized. Using 3 as the starting material, two trinuclear heterometallic complexes M(MeOH)(4)[ClRe(CO)(3)(Hbpydt)](2)center dot 2MeOH (M = Cu, 4; M = Mn, 5) are obtained. The crystal structures of 2-5 have been determined by X-ray crystallography. Complexes 4 and 5 are isostructural. Their absorption and emission properties are studied. The magnetic properties of complexes 4 and 5 have also been investigated. (c) 2010 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.05.028
• 作为产物：
  描述：

  盐酸 、 tetra-n-butylammonium hydroxide 、 (dimethyl-2(di(2-pyridyl)methylene)-1,3-dithiole-4,5-dicarboxylate)chlorotricarbonylrhenium(I) 在 KOH 作用下， 以 四氢呋喃 、 水 为溶剂， 以60%的产率得到(2-(di(2-pyridyl)methylene)-1,3-dithiole-3-carboxylic acid-4-carboxylate)chlorotricarbonylrhenium(I) tetrabutylammonium
  参考文献：
  名称：

  Syntheses, structures, and properties of tricarbonyl rhenium(I) heteronuclear complexes with the multidentate bridging ligand containing bis(2-pyridine) and carboxylic acid

  摘要：

  By deprotonation reaction of the rhenium(I) tricarbonyl complex, ClRe(CO)(3)(H(2)bpydt) (2, H(2)dpydt = 2(di(2-pyridyl) methylene)-1,3-dithiole-4,5-dicarboxylic acid, our previous work in J. Organomet. Chem. 694 (2009) 763), complex 3, [Bu4N][ClRe(CO)(3)(Hbpydt)], is synthesized and characterized. Using 3 as the starting material, two trinuclear heterometallic complexes M(MeOH)(4)[ClRe(CO)(3)(Hbpydt)](2)center dot 2MeOH (M = Cu, 4; M = Mn, 5) are obtained. The crystal structures of 2-5 have been determined by X-ray crystallography. Complexes 4 and 5 are isostructural. Their absorption and emission properties are studied. The magnetic properties of complexes 4 and 5 have also been investigated. (c) 2010 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.05.028