| 1559000-88-2

• CAS: 1559000-88-2
• 化学式: C₂₂H₃₂NO₂PPt
• 分子量: 568.555
• InChiKey: VNKUPMQSKIWRLR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [(κ²-P,N)-Ph₂PCH₂CH₂NMe₂]PtMe₂ 、 氯乙酸乙酯 以 氘代苯 为溶剂， 生成 [(κ(2)-P,N)-Ph2PCH2CH2NMe2]Pt(Me)Cl 、 [(κ(2)-P,N)-Ph2PCH2CH2NMe2]PtMe3Cl 、 、 、 、
  参考文献：
  名称：

  An NMR study on the reaction of [(κ 2-P,N)-Ph2PCH2CH2NMe2]PtMe2 with activated chlorocarbons: C–Cl and C–C activation, followed by C–N cleavage of the phosphinoalkylamine ligand and formation of an ylide complex

  摘要：

  Reaction of [(kappa (2)-P,N)-Ph2PCH2CH2NMe2]PtMe2 with either ethyl chloroacetate or benzyl chloride results in complex reaction mixtures, which were investigated by a combination of NMR techniques. The reactions are initiated by oxidative addition of either the C-Cl bond or of the C-CH2Cl bond, respectively. The latter is followed by a rearrangement of the intermediate Pt(IV) complex with concomitant C-N bond cleavage of the phosphinoalkylamine ligand and formation of the ylide complexes Pt[CH2=PPh2(vinyl)](NMe2R)Me-2 (R = COOEt or Ph).

  DOI：

  10.1007/s00706-014-1158-0