[(κ(2)-P,N)-Ph2PCH2CH2NMe2]PtMe3Cl | 484065-58-9

• 英文名称: [(κ(2)-P,N)-Ph2PCH2CH2NMe2]PtMe3Cl
• 英文别名: [(κ2-P,N)-Ph2PCH2CH2NMe2]Pt(Cl)Me3
• CAS: 484065-58-9
• 化学式: C₁₉H₂₉ClNPPt
• 分子量: 532.953
• InChiKey: RDNBCFIGLWYMNQ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [(κ²-P,N)-Ph₂PCH₂CH₂NMe₂]PtMe₂ 、 氯甲烷 以 氘代苯 为溶剂， 以99%的产率得到[(κ(2)-P,N)-Ph2PCH2CH2NMe2]PtMe3Cl
  参考文献：
  名称：

  Stoehr, Frank; Sturmayr, Dietmar; Kickelbick, Guido, European Journal of Inorganic Chemistry, 2002, # 9, p. 2305 - 2311

  摘要：

  DOI：

文献信息

• An NMR study on the reaction of [(κ 2-P,N)-Ph2PCH2CH2NMe2]PtMe2 with activated chlorocarbons: C–Cl and C–C activation, followed by C–N cleavage of the phosphinoalkylamine ligand and formation of an ylide complex
  作者：Christian Martschitsch、Ulrich Schubert

  DOI：10.1007/s00706-014-1158-0

  日期：2014.4

  Reaction of [(kappa (2)-P,N)-Ph2PCH2CH2NMe2]PtMe2 with either ethyl chloroacetate or benzyl chloride results in complex reaction mixtures, which were investigated by a combination of NMR techniques. The reactions are initiated by oxidative addition of either the C-Cl bond or of the C-CH2Cl bond, respectively. The latter is followed by a rearrangement of the intermediate Pt(IV) complex with concomitant C-N bond cleavage of the phosphinoalkylamine ligand and formation of the ylide complexes Pt[CH2=PPh2(vinyl)](NMe2R)Me-2 (R = COOEt or Ph).