mono(pentahydroxycobalt(VIII)) monochloride | 83862-38-8

• 英文名称: mono(pentahydroxycobalt(VIII)) monochloride
• CAS: 83862-38-8
• 化学式: ClCoH₁₀O₅
• 分子量: 184.523
• InChiKey: KPWWFJWTNBDKQQ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (1,4,8,11-tetraazacyclotetradecane)copper(II) ion 、 mono(pentahydroxycobalt(VIII)) monochloride 以 水 为溶剂， 生成 hexaaquacobalt(II)
  参考文献：
  名称：

  Rotzinger, François P.; Kumar, Krishan; Endicott, John F., Inorganic Chemistry, 1982, vol. 21, # 11, p. 4111 - 4112

  摘要：

  DOI：
• 作为产物：
  描述：

  cobalt (II) perchlorate hexahydrate 、 dichlorine radical anion 以 水 为溶剂， 生成 mono(pentahydroxycobalt(VIII)) monochloride
  参考文献：
  名称：

  Magnetic field effects in rates of reactions between radicals and transition metal coordination complexes of cobalt(II) and manganese(II): probes for spin polarization

  摘要：

  The effect of magnetic fields on the rates of reactions of Cl-2-, Br-2-, and CO3H with Co(II) and Mn(II) complexes was investigated as a function of the field intensity between 0 and 7 T. The Delta g mechanism and suppression of HFC-induced transitions in radical-ion pairs account for effects observed at less than 0.3 T on reactions with high-spin Co(II) complexes. In the reaction between Co(Me(6)-[14]dieneN(4))(2+) and Cl-2-, MFE on the rate are mostly related to the suppression of HFC-induced transitions in the radical-ion pairs. In a number of these processes the reaction rate constant increases with field and the sense of MFE in reactions of the CO3H radical appears inverted with respect to reactions of Cl-2- and Br-2-. A mechanism that accounts for such differences is discussed.

  DOI：

  10.1021/j100148a014