| 132492-32-1

• CAS: 132492-32-1
• 化学式: C₅₀H₅₄P₄Rh
• 分子量: 881.779
• InChiKey: HZBFYBCIOHEUKB-GHDUESPLSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 sodium thiomethoxide 以 四氢呋喃 、 甲醇 为溶剂， 以85%的产率得到(tris(2-(diphenylphosphino)ethyl)phosphine)rhodium methylthiolate
  参考文献：
  名称：

  Synthesis of a rhodium methylthiolate and insertion of CS2 into the Rh—SCH3 bond. Structure of the thioxanthate [(pp3)RhSC(S)SCH3] [pp3 = tris(2-(diphenylphosphino)ethyl)phosphine]

  摘要：

  The reaction between the (pp3)Rh(I) fragment [PP3 = tris(2-(diphenylphosphino)ethyl)phosphine, P(CH2CH2PPh2)3] and NaSCH, readily yields the methylthiolate derivative [(pp3)RhSCH3]. The sulphur atom of this compound is attacked by the electrophile CF3SO3CH3 to yield the stable dimethylsulphide complex [(pp3)RhS(CH3)2]CF3SO3. Furthermore, the rhodium methylthiolate undergoes CS2 insertion to form the thioxanthate [(pp3)RhSC(S)SCH3], Which has been characterized by a complete X-ray crystallographic analysis.

  DOI：

  10.1016/s0277-5387(00)87047-3