tetrafluoro-l4-borane, 2-(9-butyl-2,3,5,6,7,8-hexahydroacridin-4(1H)-ylidene)-1,1,1-trimethylhydrazin-1-ium salt | 99922-94-8

• 英文名称: tetrafluoro-l4-borane, 2-(9-butyl-2,3,5,6,7,8-hexahydroacridin-4(1H)-ylidene)-1,1,1-trimethylhydrazin-1-ium salt
• CAS: 99922-94-8
• 化学式: BF₄*C₂₀H₃₂N₃
• 分子量: 401.299
• InChiKey: MHVVZTAWSNYNNQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  tetrafluoro-l4-borane, 2-(9-butyl-2,3,5,6,7,8-hexahydroacridin-4(1H)-ylidene)-1,1,1-trimethylhydrazin-1-ium salt 反应 0.08h， 生成 5,11-di-n-butyl-1,2,3,4,6,7,9,10,12,13,14,15-dodecahydroacridino[4,3-b]benzo[j][1,10]phenanthroline
  参考文献：
  名称：

  Construction of a soluble heptacyclic terpyridine

  摘要：

  DOI：

  10.1021/jo00355a041
• 作为产物：
  描述：

  9-n-butyl-1,2,3,4,5,6,7,8-octahydroacridine N-oxide 在 chromium(VI) oxide 、 盐酸 、 硫酸 、 对甲苯磺酸 作用下， 以 二氯甲烷 、 溶剂黄146 为溶剂， 反应 20.67h， 生成 tetrafluoro-l4-borane, 2-(9-butyl-2,3,5,6,7,8-hexahydroacridin-4(1H)-ylidene)-1,1,1-trimethylhydrazin-1-ium salt
  参考文献：
  名称：

  Construction of a soluble heptacyclic terpyridine

  摘要：

  DOI：

  10.1021/jo00355a041

文献信息

• Molecular Architecture. 2.¹ Synthesis and Metal Complexation of Heptacyclic Terpyridyl Molecular Clefts
  作者：Thomas W. Bell、Peter J. Cragg、Albert Firestone、Albert D.-I. Kwok、Jia Liu、Richard Ludwig、Andrej Sodoma

  DOI：10.1021/jo9720041

  日期：1998.4.1

  Methods are described for the synthesis of a series of functionalized derivatives of 9-butyl-1,2,3,4,5,6,7,8-octahydroacridine (9), a building block for several types of highly preorganized host compounds. A key intermediate is 5-benzylidene-9-butyl-2,3,5,6,7,8-hexahydroacridin-4(1H)-one (23), which can also be used in the syntheses of torands and hydrogen-bonding hexagonal lattice receptors. A tridentate cleft (20), consisting of 2,2';6',2 "-terpyridine imbedded in a heptacyclic framework, and a corresponding pentadentate diketone (6) were synthesized from 9 in five and seven steps, respectively. The picrate extraction method was used to estimate the solution stabilities of alkali metal complexes of heptacyclic terpyridyls 6 and 20, which was also compared with a flexible terpyridyl (37). Alkali metal complexes of both heptacyclic terpyridyls showed relatively high K-s values, but low size selectivity. Pentadentate host 6 binds Na+ and K+ more strongly than do most hexadentate crown ethers; flexible tridentate analogue 37 failed to extract alkali metal picrates into chloroform. The complexation abilities of 6 and 20 are attributed to enforced orientation of functional group dipoles toward the center of the molecular cleft. Sodium and potassium picrate complexes of pentadentate cleft 6 were synthesized (1:1 stoichiometry), and a 2:1 complex of calcium triflate (6(2) . Ca(CF3SO3)(2)) was also prepared.