| 133597-84-9

• CAS: 133597-84-9
• 化学式: C₂F₃O₂*C₃₁H₁₈F₆HgNO₅PRh
• 分子量: 1045.96
• InChiKey: UCFQYCHYSLHNOC-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  以 乙醚 、 正己烷 、 丙酮 为溶剂， 以25-30的产率得到
  参考文献：
  名称：

  Reactivity of pyridinecarboxylate complexes of rhodium(I) towards Hg(OOCCF3)2 and Hg(Ph)(OOCCF3). Crystal structure of Rh(C10H6NO2)(OOCCF3)2(H2O)[P(4-CH3-C6H4)3]III

  摘要：

  Reactions of Rh(N-O)(CO)[P(4-X-C6H4)3][(N-O) = 2-C5NH4COO(pyC) and 2-C9NH6COO (quin), X = CH3O, CH3, F, Cl] with Hg(R)(OOCCF3) (R = Ph, OOCCF3) lead to the hexacoordinate rhodium(III), Rh(HgR)(OOCCF3)(N-O)(CO)[P(4-X-C6H4)3], complexes. The new compounds evolve in solution to the decarbonylated species Rh(R)(OOCCF3)(N-O)(H2O)[P(4-X6-C6H4)3]. The crystal of one of the above derivatives, Rh(OOCCF3)2(quin)(H2O)[P(4-CH3-C6H4)3], is reported, and a distorted octahedral coordination around the rhodium atom with the two monodentate OOCCF3 ligands in cis positions is found.

  DOI：

  10.1016/s0277-5387(00)81588-0
• 作为产物：
  描述：

  {Rh(C9NH6COO)(CO)(P(p-FC6H4)3)} 、 mercury(II) trifluoroacetate 以 丙酮 为溶剂， 生成
  参考文献：
  名称：

  Reactivity of pyridinecarboxylate complexes of rhodium(I) towards Hg(OOCCF3)2 and Hg(Ph)(OOCCF3). Crystal structure of Rh(C10H6NO2)(OOCCF3)2(H2O)[P(4-CH3-C6H4)3]III

  摘要：

  Reactions of Rh(N-O)(CO)[P(4-X-C6H4)3][(N-O) = 2-C5NH4COO(pyC) and 2-C9NH6COO (quin), X = CH3O, CH3, F, Cl] with Hg(R)(OOCCF3) (R = Ph, OOCCF3) lead to the hexacoordinate rhodium(III), Rh(HgR)(OOCCF3)(N-O)(CO)[P(4-X-C6H4)3], complexes. The new compounds evolve in solution to the decarbonylated species Rh(R)(OOCCF3)(N-O)(H2O)[P(4-X6-C6H4)3]. The crystal of one of the above derivatives, Rh(OOCCF3)2(quin)(H2O)[P(4-CH3-C6H4)3], is reported, and a distorted octahedral coordination around the rhodium atom with the two monodentate OOCCF3 ligands in cis positions is found.

  DOI：

  10.1016/s0277-5387(00)81588-0