[(η6-C6Me6)Ru(η3-NH(CH2CH2S)2)] | 823807-71-2

• 英文名称: [(η6-C6Me6)Ru(η3-NH(CH2CH2S)2)]
• CAS: 823807-71-2
• 化学式: C₁₆H₂₇NRuS₂
• 分子量: 398.599
• InChiKey: GRHMFIKYJNGOCR-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  ammonium hexafluorophosphate 、 [(η6-C6Me6)Ru(η3-NH(CH2CH2S)2)] 、 碘甲烷 以 甲醇 为溶剂， 以63%的产率得到[(η6-C6Me6)Ru(η3-NH(CH2CH2SMe)2)](I,PF6)
  参考文献：
  名称：

  Syntheses and Single-Crystal X-ray Diffraction Studies of Acyclic and Macrocyclic Aza Dithiolate (NS₂) Complexes of (Arene)ruthenium(II). Thiolate Alkylation, Base-Promoted Hydroalkylation, and Protonation Reactions

  摘要：

  The complex [(HMB)Ru{eta(3)-HN(CH2CH2S)(2)}] (2), synthesized from the reaction of [(HMB)RuCl2](2) (HMB = eta(6)-C6Me6) with HN(CH2CH2S-)(2), undergoes S-alkylation reactions with (i) Br(CH2)nBr (n 2-4), giving [(HMB)Ru{eta(3)-S(CH2)(2)NH(CH2)(2)S(CH2)(n)}](PF6)(2) (n = 2 (3), 3 (4), 4 (5)), which contain macrocyclic zNS(2) (z = 9-11) ligands, (ii) CH3I, giving [(HMB)Ru{eta(3)-NH(CH2CH2SMe)(2)}](I.PF6) (6), and (iii) bromoalkenes CH2=CH(CH2)(n)Br (n = 1, 2), yielding the S-alkenyl derivatives [(HMB)Ru{eta(3)-S(CH2)(2)NH(CH2)(2)SCH2CH=CH2}]PF6 (7), [(HMB)Ru{eta(3)-NH((CH2)(2)SCH2CH=CH2)(2)}](Br-PF6) (8), and [(HMB)Ru{eta(3)-S(CH2)(2)NH(CH2)(2)S(CH2)(2)CH=CH2}]PF6 (9). Deprotonation of 3 and 7 results in the formation of arene-tethered complexes, viz. [Ru{eta(6):eta(3)-C6Me5(CH2)(3)S(CH2)(2)NH(CH2)(2)S}]PF6 (11), from 3 via [(HMB)Ru{eta(3)-S(CH2)(2)NH(CH2)(2)SCH=CH2}]PF6 (10), which can be reverted to 3 with acid treatment, and [Ru{eta(6):eta(3)-C6Me5CH2CH(Me)CH2S(CH2)(2)NH(CH2)(2)S}]PF6 (12) from 7. The X-ray crystal structures of 2, 3, and 5-12 are reported.

  DOI：

  10.1021/om049445c
• 作为产物：
  描述：

  [RuCl2(hexamethylbenzene)]2 、 Bis-β-mercaptoethylamin 在 sodium methoxide 作用下， 以 四氢呋喃 为溶剂， 以57%的产率得到[(η6-C6Me6)Ru(η3-NH(CH2CH2S)2)]
  参考文献：
  名称：

  Syntheses and Single-Crystal X-ray Diffraction Studies of Acyclic and Macrocyclic Aza Dithiolate (NS₂) Complexes of (Arene)ruthenium(II). Thiolate Alkylation, Base-Promoted Hydroalkylation, and Protonation Reactions

  摘要：

  The complex [(HMB)Ru{eta(3)-HN(CH2CH2S)(2)}] (2), synthesized from the reaction of [(HMB)RuCl2](2) (HMB = eta(6)-C6Me6) with HN(CH2CH2S-)(2), undergoes S-alkylation reactions with (i) Br(CH2)nBr (n 2-4), giving [(HMB)Ru{eta(3)-S(CH2)(2)NH(CH2)(2)S(CH2)(n)}](PF6)(2) (n = 2 (3), 3 (4), 4 (5)), which contain macrocyclic zNS(2) (z = 9-11) ligands, (ii) CH3I, giving [(HMB)Ru{eta(3)-NH(CH2CH2SMe)(2)}](I.PF6) (6), and (iii) bromoalkenes CH2=CH(CH2)(n)Br (n = 1, 2), yielding the S-alkenyl derivatives [(HMB)Ru{eta(3)-S(CH2)(2)NH(CH2)(2)SCH2CH=CH2}]PF6 (7), [(HMB)Ru{eta(3)-NH((CH2)(2)SCH2CH=CH2)(2)}](Br-PF6) (8), and [(HMB)Ru{eta(3)-S(CH2)(2)NH(CH2)(2)S(CH2)(2)CH=CH2}]PF6 (9). Deprotonation of 3 and 7 results in the formation of arene-tethered complexes, viz. [Ru{eta(6):eta(3)-C6Me5(CH2)(3)S(CH2)(2)NH(CH2)(2)S}]PF6 (11), from 3 via [(HMB)Ru{eta(3)-S(CH2)(2)NH(CH2)(2)SCH=CH2}]PF6 (10), which can be reverted to 3 with acid treatment, and [Ru{eta(6):eta(3)-C6Me5CH2CH(Me)CH2S(CH2)(2)NH(CH2)(2)S}]PF6 (12) from 7. The X-ray crystal structures of 2, 3, and 5-12 are reported.

  DOI：

  10.1021/om049445c