2,11-diphenyl-dibenzo[h,j]-16-methyl-6,15-diaza-1,3,10,12-tetraoxa-2,11-diboracyclooctadeca-6,15-diene | 1385743-80-5

• 英文名称: 2,11-diphenyl-dibenzo[h,j]-16-methyl-6,15-diaza-1,3,10,12-tetraoxa-2,11-diboracyclooctadeca-6,15-diene
• CAS: 1385743-80-5
• 化学式: C₃₁H₃₀B₂N₂O₄
• 分子量: 516.212
• InChiKey: PEZAFEOIHRUJPR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2'-羟基苯乙酮 以 四氢呋喃 、 乙醇 、 甲苯 为溶剂， 反应 3.0h， 生成 2,11-diphenyl-dibenzo[h,j]-16-methyl-6,15-diaza-1,3,10,12-tetraoxa-2,11-diboracyclooctadeca-6,15-diene
  参考文献：
  名称：

  Synthesis, characterization and X-ray studies of new six–seven membered rings [4.5.0] heterobicyclic system of monomeric boronates

  摘要：

  Different tridentate ligands derived from ethanolamines and 2-hydroxyacetophenone, 2-hydroxybenzophenone and salicylaldehyde were reacted with two equivalents of phenylboronic acid to obtain compounds 6a-6f which are [4.5.0] heterobicyclic systems with a B-O-B structural unit. The boronates were fully characterized and two heterobicyclic [4.5.0] structures have been analyzed by X-ray crystallography, where a series of parameters such as bond distances, bond angles, torsion angles, tetrahedral character at the boron atom and deviation of the boron atom from the mean plane have been evaluated. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2012.03.055