dichloro[bis(2-diphenylphosphinoethyl)phenylphosphine](dimethyl sulfoxide)ruthenium(II) | 167467-51-8

• 英文名称: dichloro[bis(2-diphenylphosphinoethyl)phenylphosphine](dimethyl sulfoxide)ruthenium(II)
• CAS: 167467-51-8；85445-43-8
• 化学式: C₃₆H₃₉Cl₂OP₃RuS
• 分子量: 784.668
• InChiKey: PFRDWJFWZRJOEJ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  dichloro[bis(2-diphenylphosphinoethyl)phenylphosphine](dimethyl sulfoxide)ruthenium(II) 、 乙腈 以 乙腈 为溶剂， 生成 dichloro[bis(2-diphenylphosphinoethyl)phenylphosphine](CH3CN)ruthenium(II)
  参考文献：
  名称：

  X-ray structure of dichloro-[bis(2-diphenylphosphinoethyl)phenylphosphine] (dimethyl sulfoxide)ruthenium(II)

  摘要：

  The complex RuCl2(TRIPHOS)(DMSO). C6H5CH3 is monoclinic, P2(1)/c, with a=21.070(5), b=11.968(3), c=16.892(4) Angstrom, beta=107.7(2)degrees, V=4057.2 Angstrom(3), Z=4. The crystal structure consists of discrete molecules of the complex and solvent held together by normal van der Waals forces. The ruthenium atom is hexacoordinated. Dimethyl sulfoxide binds through the sulfur atom and the TRIPHOS ligand occupies three coordination sites.

  DOI：

  10.1016/0020-1693(94)04393-a
• 作为产物：
  描述：

  双(2-二苯基膦乙基)苯基磷 、 dichlorotetrakis(dimethylsulfoxide)ruthenium 以 甲苯 为溶剂， 以60%的产率得到dichloro[bis(2-diphenylphosphinoethyl)phenylphosphine](dimethyl sulfoxide)ruthenium(II)
  参考文献：
  名称：

  X-ray structure of dichloro-[bis(2-diphenylphosphinoethyl)phenylphosphine] (dimethyl sulfoxide)ruthenium(II)

  摘要：

  The complex RuCl2(TRIPHOS)(DMSO). C6H5CH3 is monoclinic, P2(1)/c, with a=21.070(5), b=11.968(3), c=16.892(4) Angstrom, beta=107.7(2)degrees, V=4057.2 Angstrom(3), Z=4. The crystal structure consists of discrete molecules of the complex and solvent held together by normal van der Waals forces. The ruthenium atom is hexacoordinated. Dimethyl sulfoxide binds through the sulfur atom and the TRIPHOS ligand occupies three coordination sites.

  DOI：

  10.1016/0020-1693(94)04393-a