4-n-butoxybenzenediazonium tetrafluoroborate | 76832-54-7

• 英文名称: 4-n-butoxybenzenediazonium tetrafluoroborate
• 英文别名: 4-n-butoxyphenyldiazonium tetrafluoroborate；4-butoxyphenyldiazonium tetrafluoroborate
• CAS: 76832-54-7
• 化学式: BF₄*C₁₀H₁₃N₂O
• 分子量: 264.031
• InChiKey: OZVKSJDDMHCKRG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  4-n-butoxybenzenediazonium tetrafluoroborate 在 氢氧化钾 、 sodium hydroxide 、 sodium carbonate 作用下， 以 水 、 丙酮 为溶剂， 反应 48.0h， 生成 4-hexyloxy-4'-butoxy-2-hydroxyazobenzene
  参考文献：
  名称：

  Complexes of liquid crystal o-hydroxyazo compounds with Cu2+ and Pd2+ ions

  摘要：

  Liquid crystal o-hydroxyazo compounds were prepared and used to give complexes with Cu2+ and Pd2+ ions. The structures of these complexes were studied by ESR, IR, and UV spectroscopy. The relationship of the structures of these complexes and their mesogenic properties was examined.

  DOI：

  10.1007/bf00959733
• 作为产物：
  描述：

  4-丁氧基苯胺 在 盐酸 、 氟硼酸钠 、 sodium nitrite 作用下， 生成 4-n-butoxybenzenediazonium tetrafluoroborate
  参考文献：
  名称：

  Complexes of liquid crystal o-hydroxyazo compounds with Cu2+ and Pd2+ ions

  摘要：

  Liquid crystal o-hydroxyazo compounds were prepared and used to give complexes with Cu2+ and Pd2+ ions. The structures of these complexes were studied by ESR, IR, and UV spectroscopy. The relationship of the structures of these complexes and their mesogenic properties was examined.

  DOI：

  10.1007/bf00959733

文献信息

• Arylazostilbene und -tolane durch Heck-Reaktion
  作者：Cheung-Bok Jeoung、Oliver Haak、Walter Grahn、Peter Boldt

  DOI：10.1002/prac.19933350605

  日期：——

  The palladium-catalysed coupling of p-bromo azo dyes 4 with styrenes 6 and arylacetylenes 9 provides arylazostilbenes 7 and -tolanes 10, respectively, in fair-to-good yields. Likewise, coupling of azoxy compound 5 with styrenes 6 forms the arylazoxystilbenes 8 in high yields. The influence of substituentes on light absorption of the new dyes as well as on the the C-13-NMR shifts of the azotolanes 10 are discussed.
• Haak, Oliver; Jeoung, Cheung-Bok; Pawlik, Andreas, Journal of Chemical Research, Miniprint, 1998, # 10, p. 2701 - 2735
  作者：Haak, Oliver、Jeoung, Cheung-Bok、Pawlik, Andreas、Boldt, Peter、Grahn, Walter、et al.

  DOI：——

  日期：——
• Crown cation complex effects. 12. Dissolution and complexation of arenediazonium cations in nonpolar media. An assessment of solvent effects and reactivity by infrared and nuclear magnetic resonance spectroscopy
  作者：Stephen H. Korzeniowski、Ahuva Leopold、James R. Beadle、Michael F. Ahern、William A. Sheppard、Raj K. Khanna、George W. Gokel

  DOI：10.1021/jo00323a036

  日期：1981.5