(η(5)-C5H5)Fe(CO)(CN)(CNFe(CO)2(η(5)-C5H5)) | 201555-61-5

• 英文名称: (η(5)-C5H5)Fe(CO)(CN)(CNFe(CO)2(η(5)-C5H5))
• CAS: 201555-61-5
• 化学式: C₁₅H₁₀Fe₂N₂O₃
• 分子量: 377.95
• InChiKey: ZDYPYLGTNPFWFM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  六羰基钨 、 (η(5)-C5H5)Fe(CO)(CN)(CNFe(CO)2(η(5)-C5H5)) 在 THF 作用下， 以 四氢呋喃 为溶剂， 以24%的产率得到(η(5)-C5H5)Fe(CO)(CNFe(CO)2(η(5)-C5H5))(CNW(CO)5)
  参考文献：
  名称：

  Synthesis and spectroscopic properties of heteropolynuclear cyano-bridged complexes

  摘要：

  The heteropolynuclear cyano-bridged complexes [(C(5)H(5))Fe(CO)(CNMLn)(CNM'L'n)], {MLn = M'L'n = (C(5)H(5))Fe(CO)(2) or W(CO)(5); MLn = (C(5)H(5))Fe(CO)(2), M'L'n = W(CO)(5)} and mixed isocyanide complexes [(C(5)H(5))Fe(CO)(CNMLn)(CNR)], {MLn = W(CO)(5), R = CPh(3); MLn = (C(5)H(5))Fe(CO)(2), R = CH(3)} have been obtained by metallation or alkylation of the two terminal CN ligands of K[(C(5)H(5))Fe(CO)(CN)(2)]. Comparison of the bonding properties of the CNMLn and CNR ligands, based upon their relevant spectroscopic data, are discussed. Furthermore, two new isomeric heterobinuclear cyano-bridged complexes of the form [(C(5)H(5))(CO)(2)FeCNW(CO)(5)] and [(C(5)H(5))(CO)(2)FeNCW(CO)(5)] have been synthesized and fully characterized by spectroscopic techniques. Finally the reactions with nucleophiles of the last two compounds have been also examined. (C) 1997 Elsevier Science S.A.

  DOI：

  10.1016/s0022-328x(97)00352-5
• 作为产物：
  描述：

  cyclopentadienyldicarbonyl(tetrahydrofuran)iron(II) tetrafluoroborate 、 potassium cyclopentadienylcarbonyldicyanoferrate(II) 以 四氢呋喃 为溶剂， 以19%的产率得到(η(5)-C5H5)Fe(CO)(CN)(CNFe(CO)2(η(5)-C5H5))
  参考文献：
  名称：

  Synthesis and spectroscopic properties of heteropolynuclear cyano-bridged complexes

  摘要：

  The heteropolynuclear cyano-bridged complexes [(C(5)H(5))Fe(CO)(CNMLn)(CNM'L'n)], {MLn = M'L'n = (C(5)H(5))Fe(CO)(2) or W(CO)(5); MLn = (C(5)H(5))Fe(CO)(2), M'L'n = W(CO)(5)} and mixed isocyanide complexes [(C(5)H(5))Fe(CO)(CNMLn)(CNR)], {MLn = W(CO)(5), R = CPh(3); MLn = (C(5)H(5))Fe(CO)(2), R = CH(3)} have been obtained by metallation or alkylation of the two terminal CN ligands of K[(C(5)H(5))Fe(CO)(CN)(2)]. Comparison of the bonding properties of the CNMLn and CNR ligands, based upon their relevant spectroscopic data, are discussed. Furthermore, two new isomeric heterobinuclear cyano-bridged complexes of the form [(C(5)H(5))(CO)(2)FeCNW(CO)(5)] and [(C(5)H(5))(CO)(2)FeNCW(CO)(5)] have been synthesized and fully characterized by spectroscopic techniques. Finally the reactions with nucleophiles of the last two compounds have been also examined. (C) 1997 Elsevier Science S.A.

  DOI：

  10.1016/s0022-328x(97)00352-5