[Mo(CO)3(dppe)(py)] | 19349-52-1

• 英文名称: [Mo(CO)3(dppe)(py)]
• 英文别名: [Mo(CO)₃(dppe)(py)]；fac-((pyridine)-1,2-bis(diphenylphosphino)ethane)Mo(CO)3
• CAS: 19349-52-1
• 化学式: C₃₄H₂₉MoNO₃P₂
• 分子量: 657.497
• InChiKey: JQIBHWCLVWNYFY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [Mo(CO)3(dppe)(py)] 在 PPh₃ 作用下， 以 吡啶 为溶剂， 生成 fac-{(PPh3)-1,2-bis(diphenylphosphino)ethane}Mo(CO)3
  参考文献：
  名称：

  Asali, Khalil J.; Van Zyl, Gideon J.; Dobson, Gerard R., Inorganic Chemistry, 1988, vol. 27, # 19, p. 3314 - 3319

  摘要：

  DOI：
• 作为产物：
  描述：

  [1,2-双(二苯基膦)乙烷]四羰基钼(0) 在 pyridine 作用下， 以 四氢呋喃 、 正己烷 、 甲苯 为溶剂， 以82%的产率得到[Mo(CO)3(dppe)(py)]
  参考文献：
  名称：

  Asali, Khalil J.; Van Zyl, Gideon J.; Dobson, Gerard R., Inorganic Chemistry, 1988, vol. 27, # 19, p. 3314 - 3319

  摘要：

  DOI：

文献信息

• Schenk, Wolfdieter A.; Mueller, Helmut, Chemische Berichte, 1982, vol. 115, # 11, p. 3618 - 3630
  作者：Schenk, Wolfdieter A.、Mueller, Helmut

  DOI：——

  日期：——
• Metal-Template-Controlled Stabilization of β-Functionalized Isocyanides
  作者：A. Carolin Dumke、Tania Pape、Jutta Kösters、Kai-Oliver Feldmann、Christian Schulte to Brinke、F. Ekkehardt Hahn

  DOI：10.1021/om301067v

  日期：2013.1.14

  Reaction of 2-azidoethyl isocyanide 1, 2-azidophenyl isocyanide 2, or 2-nitrophenyl isocyanide 3 with complexes [Mo(CO)(3)(dppe)(py)] [4] or [W(CO)(3)(dppe)(NE CCH3)] [5] yields the isocyanide complexes [Mo(CO)(3)(dppe)(C NR)] ([6]: C NR = 1; [12]: C NR = 2; [13]: C NR = 3) and [W(CO)(3)(dppe)(C NR)] ([7]: C NR = 1; [14]: C NR = 2; [15]: C NR = 3). Reduction of the nitro or azido groups attached to the isocyanide figands by Zn/NH4Cl (azidoethyl or azidophenyl isocyanides) or Raney-nickel/hydrazine hydrate (nitrophenyl isocyanide) yields exclusively the complexes bearing the 2-amino-functionalized isocyanides. The normally unstable 2-amino-functionalized isocyanides are stabilized by M -> C NR back-bonding, which deactivates the isocyanide carbon atom for an intramolecular nucleophilic attack by the primary amine.
• The chemical reactivity of fullerene C60 towards fac-Mo(CO)3 (MeCN)(dppe) and Mo(CO)4(dppe). Synthesis, characterization and reactions of the novel fullerene molybdenum derivative fac-Mo(CO)3(dppe)(η2-C60)
  作者：Li-Cheng Song、Ying-Huai Zhu、Qing-Mei Hu

  DOI：10.1016/s0277-5387(97)00370-7

  日期：1998.1

  The acetonitrile ligand of fac-Mo(CO)(3)(MeCN)(dppe)[dppe = bis-(1,2-diphenylphosphino)ethane] can be easily replaced by fullerene C-60 in chlorobenzene at about 80 degrees C to give exclusively fac-Mo(CO)(3)(dppe>(eta(2)-C-60), whereas fullerene C-60 reacted with Mo(CO)(4)(dppe) in refluxing chlorobenzene to afford an isomeric mixture of fac- and mer-Mo(CO)(3)(dppe)(eta(2)-C-60). These organomolybdenum C-60 derivatives were characterized by elemental analysis and spectroscopic techniques. In addition, the eta(2)-C-60 ligand in fac-Mo(CO)(3)(dppe)(eta(2)-C-60) was also found to be easily displaced by MeCN, PPh3 or pyridine to give corresponding fac-organomolybdenum complexes. (C) 1998 Elsevier Science Ltd. All rights reserved.