1-(ferrocenylbutyl)-3-methylimidazolium bromide | 908834-20-8

• 英文名称: 1-(ferrocenylbutyl)-3-methylimidazolium bromide
• CAS: 908834-20-8
• 化学式: Br*C₁₈H₂₃FeN₂
• 分子量: 403.145
• InChiKey: HAQUGJLCJUPMLD-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  ammonium hexafluorophosphate 、 1-(ferrocenylbutyl)-3-methylimidazolium bromide 以95%的产率得到1-(ferrocenylbutyl)-3-methylimidazolium hexafluorophosphate
  参考文献：
  名称：

  Synthesis, characterization, and electrochemical properties of ferrocenylimidazolium

  摘要：

  A series of ferrocene-based methylimidazolium receptors were prepared and their electrochemical properties of sensing the various anions, the dependence of alkyl chain length, were investigated by voltammetry technologies. All of these ferrocenylimidazolium compounds were fully characterized by elemental analysis, NMR and mass spectrometry. Moreover, the structures of ferrocene-based methylimidazolium receptors 1a, 1b, 2b, and 3b were confirmed by X-ray crystallography. The ferrocenylimidazolium 1a and 2a receptors in which the ferrocene center and methylimidazolium fragments are directly linked showed redox waves for both the ferrocenyl moiety and the methylimidazolium moiety and exhibited rather strong electrochemical sensing properties for F- anion. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2012.12.028
• 作为产物：
  描述：

  N-甲基咪唑 、 4-bromobutylferrocene 以65%的产率得到1-(ferrocenylbutyl)-3-methylimidazolium bromide
  参考文献：
  名称：

  Synthesis, characterization, and electrochemical properties of ferrocenylimidazolium

  摘要：

  A series of ferrocene-based methylimidazolium receptors were prepared and their electrochemical properties of sensing the various anions, the dependence of alkyl chain length, were investigated by voltammetry technologies. All of these ferrocenylimidazolium compounds were fully characterized by elemental analysis, NMR and mass spectrometry. Moreover, the structures of ferrocene-based methylimidazolium receptors 1a, 1b, 2b, and 3b were confirmed by X-ray crystallography. The ferrocenylimidazolium 1a and 2a receptors in which the ferrocene center and methylimidazolium fragments are directly linked showed redox waves for both the ferrocenyl moiety and the methylimidazolium moiety and exhibited rather strong electrochemical sensing properties for F- anion. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2012.12.028

文献信息

• Redox Ionic Liquid Phases:  Ferrocenated Imidazoliums
  作者：Ramjee Balasubramanian、Wei Wang、Royce W. Murray

  DOI：10.1021/ja0625327

  日期：2006.8.1

  This communication reports the synthesis of new intrinsically electroactive N-alkyl imidazolium ionic liquids useful for the investigation of charge transport phenomena in undiluted semisolid redox media. The redox site chosen is ferrocene, but the overall approach should be general for designing imidazolium-based molten salts. The ferrocene is attached to imidazolium with several structural variations, and preliminary voltammetry of a melt is presented.