[RuCl2(4-bromo-2,2'-bipyridine)2] | 1228182-23-7

• 英文名称: [RuCl2(4-bromo-2,2'-bipyridine)2]
• 英文别名: [RuCl2(bpyBr)2]
• CAS: 1228182-23-7
• 化学式: C₂₀H₁₄Br₂Cl₂N₄Ru
• 分子量: 642.142
• InChiKey: NGVYJVQTQZRNPO-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  ammonium hexafluorophosphate 、 [RuCl2(4-bromo-2,2'-bipyridine)2] 、 乙酰丙酮 在 KOH 作用下， 以 H₂O 为溶剂， 以90.6%的产率得到[Ru(bpyBr)2(acac)][PF6]
  参考文献：
  名称：

  Synthesis and characterization of β-diketonato ruthenium(II) complexes with two 4-bromo or protected 4-ethynyl-2,2′-bipyridine ligands

  摘要：

  Two new mononuclear mixed-ligand ruthenium(II) complexes with acetylacetonate ion (2,4-pentanedionate, acac) and functionalized bipyridine (bpy) in position 4, [Ru(bpyBr)(2)(acac)](PF(6)) (2; bpyBr = 4-Bromo-2,2'-bipyridine, acac = 2,4-pentanedionate ion) and [Ru(bpyOH)(2)(acac)](PF(6)) (3; bpyOH = 4-[2-methyl-3-butyn-2-ol]-2,2'-bipyridine) were prepared as candidates for building blocks. The (1)H NMR, (13)C NMR, UV-Vis, electrochemistry and FAB mass spectral data of these complexes are presented. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.12.057
• 作为产物：
  描述：

  水合三氯化钌 、 4-溴-2,2'-联吡啶 在 glucose 、 L-ascorbic acid 作用下， 以 ethane-1,2-diol 、 H₂O 为溶剂， 以84%的产率得到[RuCl2(4-bromo-2,2'-bipyridine)2]
  参考文献：
  名称：

  Synthesis and characterization of β-diketonato ruthenium(II) complexes with two 4-bromo or protected 4-ethynyl-2,2′-bipyridine ligands

  摘要：

  Two new mononuclear mixed-ligand ruthenium(II) complexes with acetylacetonate ion (2,4-pentanedionate, acac) and functionalized bipyridine (bpy) in position 4, [Ru(bpyBr)(2)(acac)](PF(6)) (2; bpyBr = 4-Bromo-2,2'-bipyridine, acac = 2,4-pentanedionate ion) and [Ru(bpyOH)(2)(acac)](PF(6)) (3; bpyOH = 4-[2-methyl-3-butyn-2-ol]-2,2'-bipyridine) were prepared as candidates for building blocks. The (1)H NMR, (13)C NMR, UV-Vis, electrochemistry and FAB mass spectral data of these complexes are presented. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.12.057