(cyclopentadienyl)2(tricobalt)(μ3-carbonyl)2(pentamethylcyclopentadienyl)2 | 112532-14-6

• 英文名称: (cyclopentadienyl)2(tricobalt)(μ3-carbonyl)2(pentamethylcyclopentadienyl)2
• CAS: 112532-14-6
• 化学式: C₂₂H₂₅Co₃O₂
• 分子量: 498.419
• InChiKey: QWYYXRIAWUIWOB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (cyclopentadienyl)2(tricobalt)(μ3-carbonyl)2(pentamethylcyclopentadienyl)2 在 一氧化碳 作用下， 生成
  参考文献：
  名称：

  几个含有铑或钴以及环戊二烯基或五甲基环戊二烯基配体的不寻常的三核簇的合成，表征和反应性

  摘要：

  DOI：

  10.1021/om00093a036
• 作为产物：
  描述：

  η5-cyclopentadienylbis(ethene)cobalt 、 [(pentamethylcyclopentadienyl)Co(CO)2] 以 乙醚 、 正己烷 为溶剂， 以94%的产率得到(cyclopentadienyl)2(tricobalt)(μ3-carbonyl)2(pentamethylcyclopentadienyl)2
  参考文献：
  名称：

  Barnes, Craig E.; Dial, Michelle R.; Orvis, Jeffery A., Organometallics, 1990, vol. 9, # 4, p. 1021 - 1035

  摘要：

  DOI：

文献信息

• King, William D.; Barnes, Craig E.; Orvis, Jeffery A., Organometallics, 1997, vol. 16, p. 2152 - 2159
  作者：King, William D.、Barnes, Craig E.、Orvis, Jeffery A.

  DOI：——

  日期：——
• Methylidene and hydrazone complexes of the cluster family: Cp′3M3(CO)2(CH2) (M=Co, Rh, Ir)
  作者：Frank Holger Försterling、Craig E. Barnes

  DOI：10.1016/s0022-328x(00)00712-9

  日期：2001.1

  The reactions of diazoalkanes and trinuclear complexes of the form Cp'M(CpCo)(2)(CO)(2) are described where Cp' is one of several types of cyclopentadienyl ligands and M is either Co, Rh and Ir. Two types of products which preserve the trinuclear cluster skeleton are formed: the methylidene complex, reflecting loss of dinitrogen and incorporation of the methylidene ligand, and the hydrazone complex where incorporation of the intact diazoalkane occurs. NMR and X-ray structural investigations define the general and specific structural elements of these two product types. More detailed NMR investigations have been used to monitor the dynamic behavior of the methylidene ligand in these complexes. In several instances both degenerate and nondegenerate movement of this ligand in concert with the carbonyl ligands is observed. (C) 2001 Elsevier Science B.V. All rights reserved.