[PtCl(C6H3(CH2P(iPr)2)2)] | 871132-88-6

• 英文名称: [PtCl(C6H3(CH2P(iPr)2)2)]
• 英文别名: (PCP)PtCl
• CAS: 871132-88-6
• 化学式: C₂₀H₃₅ClP₂Pt
• 分子量: 567.978
• InChiKey: BYODFRIJWRTLCO-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [PtCl(C6H3(CH2P(iPr)2)2)] 以 四氢呋喃 为溶剂， 生成 Pt(C6H3(CH2P(iPr)2)2)(triflate)
  参考文献：
  名称：

  C-Metalated Diazoalkane Complexes of Platinum Based on PCP- and PCN-Type Ligands

  摘要：

  A series of the first C-metalated diazoalkane complexes of Pt, based on pincer-type PCN and PCP ligands (PCP = C6H3[CH2P(iPr)(2)](2); PCN = C6H3[CH2P(tBu)(2)](CH2)(2)N(CH3)(2)), with the general formula (PCX)Pt[C(N-2)RI (2, X = N, R = Ph; 3, X = N, R = SiMe3; 5, X = P, R = Ph) were prepared via direct nucleophilic attack of RCN2-Li+ at the metal center. These remarkably stable complexes were characterized by H-1, P-31{H-1}, and C-13 NMR and IR spectroscopy. Complex 2 was also characterized by single-crystal X-ray crystallography. Reactions of the C-metalated diazoalkane Pt complexes with Cu(I) (reported to catalyze decomposition of diazoalkanes) were strongly influenced by the nature of the pincer ligand. Bimolecular coupling to generate diphenylacetylene and (PCP)Pt-OTf (6) was observed in the case of the rigid PCP-based complex 5, while the hemilabile PCN-based complex 2 was converted to an ylide-bridged dimeric structure, the formation of which was promoted by the decoordination of the ligand amine arm. In addition, formation of the stable metalsubstituted azine-type binuclear complex 10, generated by reaction of 2 with Rh-2(OAc)(4), is described.

  DOI：

  10.1021/om050637x
• 作为产物：
  描述：

  chloromethyl(1,5-cyclooctadiene)platinum(II) 、 [1,3-亚苯基二(亚甲基)]二(二异丙基膦) 以 甲苯 为溶剂， 以85%的产率得到[PtCl(C6H3(CH2P(iPr)2)2)]
  参考文献：
  名称：

  C-Metalated Diazoalkane Complexes of Platinum Based on PCP- and PCN-Type Ligands

  摘要：

  A series of the first C-metalated diazoalkane complexes of Pt, based on pincer-type PCN and PCP ligands (PCP = C6H3[CH2P(iPr)(2)](2); PCN = C6H3[CH2P(tBu)(2)](CH2)(2)N(CH3)(2)), with the general formula (PCX)Pt[C(N-2)RI (2, X = N, R = Ph; 3, X = N, R = SiMe3; 5, X = P, R = Ph) were prepared via direct nucleophilic attack of RCN2-Li+ at the metal center. These remarkably stable complexes were characterized by H-1, P-31{H-1}, and C-13 NMR and IR spectroscopy. Complex 2 was also characterized by single-crystal X-ray crystallography. Reactions of the C-metalated diazoalkane Pt complexes with Cu(I) (reported to catalyze decomposition of diazoalkanes) were strongly influenced by the nature of the pincer ligand. Bimolecular coupling to generate diphenylacetylene and (PCP)Pt-OTf (6) was observed in the case of the rigid PCP-based complex 5, while the hemilabile PCN-based complex 2 was converted to an ylide-bridged dimeric structure, the formation of which was promoted by the decoordination of the ligand amine arm. In addition, formation of the stable metalsubstituted azine-type binuclear complex 10, generated by reaction of 2 with Rh-2(OAc)(4), is described.

  DOI：

  10.1021/om050637x

文献信息

• Reactivity and stability of platinum(ii) formyl complexes based on PCP-type ligands. The significance of sterics
  作者：Dana Vuzman、Elena Poverenov、Yael Diskin-Posner、Gregory Leitus、Linda J. W. Shimon、David Milstein

  DOI：10.1039/b711444c

  日期：——

  C(6)H(4)[CH(2)P(tBu)(2)](2) ((tBu)PCP) are described. The chloride complex ((iPr)PCP)PtCl (6) and the unsaturated cationic complexes [(PCP)Pt](+)X(-) (X = OTf(-), BF(4)(-)) (1, 7), based on both PCP ligands, were prepared and the latter reacted with carbon monoxide to give the corresponding cationic carbonyl complexes [(PCP)Pt(CO)](+)X(-) (X = OTf(-), BF(4)(-)) (2, 8a). Hydride nucleophilic attack on both carbonyl

  基于PCP型钳形配体C（6）H（4）[CH（2）P（iPr）（2）]（2）（（描述了iPr）PCP和C（6）H（4）[CH（2）P（tBu）（2）]（2）（（tBu）PCP）。氯化物络合物（（iPr）PCP）PtCl（6）和不饱和阳离子络合物[（PCP）Pt]（+）X（-）（X = OTf（-），BF（4）（-））（1， 7）基于两种PCP配体制备，后者与一氧化碳反应生成相应的阳离子羰基配合物[（PCP）Pt（CO）]（+）X（-）（X = OTf（-），BF （4）（-））（2，8a）。氢化物对两种羰基配合物的亲核攻击导致稀有的中性铂甲酰基配合物（（iPr）PCP）Pt（CHO）（3）和（（tBu）PCP）Pt（CHO）（9）。在室温下数小时内，配合物3会进行脱羰基反应生成相应的氢化物配合物，而较大的络合物9更稳定并且仅在3-4天后才进行完全脱羰。该观察结果表明配体对相应甲酰基复合物的稳