nido-9'-thiadecaborano-{6',7':5,6}-nido-9-thiadecaborane | 157107-05-6

• 英文名称: nido-9'-thiadecaborano-{6',7':5,6}-nido-9-thiadecaborane
• 英文别名: anti-9,9'-S2B16H16；[n-S2B16H16]
• CAS: 157107-05-6
• 化学式: B₁₆H₁₆S₂
• 分子量: 253.235
• InChiKey: AVOFHOWJRVCNQG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  nido-9'-thiadecaborano-{6',7':5,6}-nido-9-thiadecaborane 在 air 作用下， 以 not given 为溶剂， 生成 1-thia-closo-dodecaborane(11)
  参考文献：
  名称：

  Macropolyhedral boron-containing cluster chemistry. Aspects of the S2B16H16 system. Preparation, structure, NMR spectroscopy and isomerism

  摘要：

  Thermolysis of [arachno-4-SB8H12] (1) in boiling cyclohexane gives two isomers 2 and 3 of 18-vertex [S2B16H16], together with known 12-vertex [closo-1-SB11H11] (4) and known 11-vertex [nido-7-SB10H12] (5). Compounds 2 and 3 are characterised by single-crystal X-ray diffraction analyses and single- and double-resonance B-11- and H-1-NMR spectroscopy. The [n-S2B16H16] isomer 2 takes the form of nido ten-vertex: nido ten-vertex [anti-B18H22] with the 9 and 9' positions occupied by S vertices, whereas the [iso-S2B16H16] isomer 3 takes the form of a nido 11-vertex {SB10} subcluster fused via a common two-boron edge to a nido-type {B-8} subcluster that is additionally linked exo to the {SB10} subcluster by a bridging S atom that is held endo to the {B-8} unit. Isomer 2 is readily deprotonated and its monoanion 6 is characterised by NMR spectroscopy and by a single-crystal X-ray diffraction analysis of its [tmndH](+)[n-S2B16H15] salt 6b; deprotonation has occurred from an open-face B-H-B bridging site. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(03)00467-4
• 作为产物：
  描述：

  arachno-4-SB8H12 以 环己烷 为溶剂， 以18%的产率得到nido-9'-thiadecaborano-{6',7':5,6}-nido-9-thiadecaborane
  参考文献：
  名称：

  Macropolyhedral boron-containing cluster chemistry. Cluster fusion to give the novel nido–nido eighteen-vertex dithiaoctadecaborane (anti)-[9,9′-S₂B₁₆H₁₆]

  摘要：

  在环己烷中热解箭毒-4-SB8H12，通过一种以前对杂硼烷物种未曾实现过的简单簇融合，生成了十八涡二硫硼烷（反）-[9,9â²-S2B16H16]â。

  DOI：

  10.1039/c39940001415

文献信息

• Macropolyhedral boron-containing cluster chemistry. [PtMe2(PMe2Ph)2] as a cluster metallating agent. Isolation and characterisation of nineteen-vertex [(PMe2Ph)HPt-η4-syn-B18H19(PMe2Ph)] and eighteen-vertex [(PMe2Ph)2PtS2B15H14(NHCOMe]
  作者：Pervinder Kaur、Annette Brownless、Sarath D Perera、Paul A Cooke、Tomáš Jelı́nek、John D Kennedy、Bohumil Štı́br、Mark Thornton-Pett

  DOI：10.1016/s0022-328x(97)00666-9

  日期：1998.4

  [PtMe2(PMe2Ph)(2)] reacts quantitatively with [nido-B10H14], [arachno-4-SB8H12] and [nido-7-SB10H12] to give [(PMe2Ph)(2)PtB10H12], [(PMe2Ph)(2)PtSB8H10] and [(PMe2Ph)(2)PtSB10H10]. With [syn-B18H22] it gives nineteen-vertex [(PMe2Ph)HPtn(4)-syn-B18H19(PMe2Ph)](1) and only smaller amounts of [(PMe2Ph)(2)Pt-n(4)-syn-B18H20], whereas with [(anti)-9,9'-S2B16H16] a complex product mixture is generated from which eighteen-vertex [(PMe2Ph)(2)Pts(2)B(15)H(14)(NHCOMe)](1) is isolatable after treatment with MeCN in air. (C) 1998 Elsevier Science S.A. All rights reserved.
• Kaur, Pervinder; Kennedy, John D.; Thornton-Pett, Mark, Journal of the Chemical Society, Dalton Transactions, 1996, p. 1775 - 1778
  作者：Kaur, Pervinder、Kennedy, John D.、Thornton-Pett, Mark、Jelinek, Tomas、Stibr, Bohumil

  DOI：——

  日期：——