trans-(triphenylphosphine)3PtCl(1+) | 47899-38-7

• 英文名称: trans-(triphenylphosphine)3PtCl(1+)
• CAS: 47899-38-7
• 化学式: C₅₄H₄₅ClP₃Pt
• 分子量: 1017.41
• InChiKey: YZBTXQSGNSDQJY-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  tin(II) chloride dihdyrate 、 trans-[PtCl((13)CO)(P(C6H5)3)2](SO3CF3) 以 氘代丙酮 、 丙酮 为溶剂， 生成 trans-(triphenylphosphine)3PtCl(1+) 、 trans-[PtCl(SnCl3)2(P(C6H5)3)](1-)
  参考文献：
  名称：

  Anderson, Gordon K.; Clark, Howard C.; Davies, Julian A., Inorganic Chemistry, 1983, vol. 22, # 3, p. 434 - 438

  摘要：

  DOI：

文献信息

• Coordination chemistry of the metalloligand [Pt2(μ-S)2(PPh3)4] with nickel(II) complexes – an electrospray mass spectrometry directed synthetic study
  作者：S.-W. Audi Fong、T.S.Andy Hor、Jagadese J. Vittal、William Henderson、Shelley Cramp

  DOI：10.1016/j.ica.2003.03.002

  日期：2004.3

  The reactivity of [Pt-2(mu-S)(2)(PPh3)(4)] towards a range of nickel(II) complexes has been probed using electrospray ionisation mass spectrometry coupled with synthesis and characterisation in selected systems. Reaction of [Pt-2(mu-S)(2)(PPh3)(4)] with [Ni(NCS)(2)(PPh3)(2)] gives [Pt-2(mu-S)(2)(PPh3)(4)Ni(NCS)(PPh3)](+), isolated as its BPh4- salt; the same product is obtained in the reaction of [Pt-2(mu-S),(PPh3)(4)] with [NiBr2(PPh3)(2)] and KNCS. An X-ray structure determination reveals the expected sulfide-bridged structure, with an N-bonded thiocyanate ligand and a square-planar coordination geometry about nickel. A range of nickel(II) complexes NIL2, containing beta-diketonate, 8-hydroxyquinolinate, or salicylaldehyde oximate ligands react similarly, giving [Pt-2(mu-S)(2)(PPh3)(4)NiL](+) cations. (C) 2003 Elsevier B.V. All rights reserved.