Co(II)(adenine)2Cl2 | 81859-88-3

• 英文名称: Co(II)(adenine)2Cl2
• 英文别名: Co(Ad)2Cl2
• CAS: 81859-88-3；144885-36-9
• 化学式: C₁₀H₁₀Cl₂CoN₁₀
• 分子量: 400.156
• InChiKey: RLKWKZPEPQWBJW-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  四苯基卟啉 、 Co(II)(adenine)2Cl2 以 二甲基亚砜 为溶剂， 以0%的产率得到cobalt(II) 5,10,15,20-tetraphenylporphyrin
  参考文献：
  名称：

  Interaction of porphyrins with adenine and adenosine complexes. Effect of a metal nature

  摘要：

  Reactions of complex formation of 5,10,15,20-tetraphenylporphine (H2TPP) and tetra-tert-butylphthalocyanine (H-2)(t-Bu)(4)Pc) with adenine and adenosine complexes of d-metals in DMSO and ethanol are studied. It was found that H2TPP reacts with Cu(II) and Hg(II) adeninates and adenosinates in DMSO, but does not react with Zn(II), Co(II), and Cd(II) adeninates and adenosinates (with both bridging and monodentate type of the ligand coordination). H-2(t-Bu)(4)Pc enters the complex formation reaction with adeninates and adenosinates of all studied metals in DMSO at almost equal rates. The states of adenine and adenosine complexes of different d-metals in DMSO and ethanol are proposed on the basis of kinetic data obtained.

  DOI：

  10.1134/s1070328406040087