[iron(II)(C5H4C(CH3)(C2H5)OH)2] | 72345-30-3

• 英文名称: [iron(II)(C5H4C(CH3)(C2H5)OH)2]
• CAS: 72345-30-3；12290-22-1；72345-33-6
• 化学式: C₁₈H₂₆FeO₂
• 分子量: 330.25
• InChiKey: OJFYUTQPFZRDFP-NAWJVIAPSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [iron(II)(C5H4C(CH3)(C2H5)OH)2] 、 4,5-dichloroisothiazole-3-carbonyl chloride 在 sodium hydride 作用下， 以 四氢呋喃 为溶剂， 反应 26.0h， 以68%的产率得到1,1'-bis[2-(4,5-dichloroisothiazole-3-carbonyloxyl)-2-butyl]ferrocene
  参考文献：
  名称：

  Synthesis of esters of metallocene alcohols and 4,5-dichloroisothiazol-3-carboxylic and 5-arylisoxazole-3-carboxylic acids

  摘要：

  Acylation of alkyl- and 1,1'-dialkylferrocene alcohols and diols as well as (3,4,4-trichlorobut-3-ene-1-ol-1-yl)-4,5-cymantrene with dichloroisothiazole- and 5-arylisoxazole-3-carbonyl chlorides has afforded esters containing 1,2-azoles fragments. Some of the obtained compounds have exhibited potentiating action in the binary mixtures with insecticides.

  DOI：

  10.1134/s1070363216020237
• 作为产物：
  描述：

  1,1'-diacetylferrocene 、 乙基溴化镁 以 乙醚 为溶剂， 生成 [iron(II)(C5H4C(CH3)(C2H5)OH)2]
  参考文献：
  名称：

  Synthesis of esters of metallocene alcohols and 4,5-dichloroisothiazol-3-carboxylic and 5-arylisoxazole-3-carboxylic acids

  摘要：

  Acylation of alkyl- and 1,1'-dialkylferrocene alcohols and diols as well as (3,4,4-trichlorobut-3-ene-1-ol-1-yl)-4,5-cymantrene with dichloroisothiazole- and 5-arylisoxazole-3-carbonyl chlorides has afforded esters containing 1,2-azoles fragments. Some of the obtained compounds have exhibited potentiating action in the binary mixtures with insecticides.

  DOI：

  10.1134/s1070363216020237

文献信息

• A Chiral Concave-Bound Cyclopentadienyl Iron Complex of Sumanene
  作者：Hiroyuki Sakane、Toru Amaya、Toshiyuki Moriuchi、Toshikazu Hirao

  DOI：10.1002/anie.200805567

  日期：——

  rotation of the cyclopentadienyl (Cp) ring is restricted in two concave‐bound monoalkyl‐substituted [CpFe(η6‐sumanene)]+ “π‐bowl” complexes (see picture). The asymmetric stacking of atropisomers was observed with a MeCpFe complex in the solid state and the chiral (S)‐sBuCpFe complex showed magnetic and optical desymmetrization of the sumanene ligand, which is the first example of a chiral complex of a π‐bowl

  大碗火的：环戊二烯基（CP）环的旋转在两个凹-结合的单烷基取代[CPFe的量（η被限制6 -sumanene）] + “π-碗”复合物（见图）。固态的MeCPFe配合物观察到阻转异构体的不对称堆积，手性（S）-s BuCPFe配合物显示了Suanene配体的磁性和光学去对称化，这是π碗配体的手性配合物的第一个例子。