| 166897-60-5

• CAS: 166897-60-5
• 化学式: C₄₄H₄₁Cl₃N₄O₂PRu
• 分子量: 896.238
• InChiKey: MUHWCBCSAUEUCX-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 亚碘酰苯 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  Synthesis, crystal structure and catalytic activities of [RuIII(bbpc)(PPh3)Cl][H2bbpc = 1,2-bis(4-tert-butylpyridine-2-carboxamido)-4,5-dichlorobenzene]

  摘要：

  The compound H(2)bbpc [1,2-bis(4-tert-butylpyridine-2-carboxamido)-4,5-dichlorobenzene], which has good solubility in organic solvents, has been prepared. Reaction of [Ru(PPh(3))(3)Cl-2] with H(2)bbpc in ethanol and in the presence of triethylamine gave [Ru-II(bbpc)(PPh(3))Cl], the crystal structure of which has been determined. This complex is an active catalyst for alkene epoxidation by PhlO, cyclopropanation of styrene by ethyl diazoacetate and aziridination of styrene by PhlNO(2)SC(6)H(4)Me-p. Its cyclic voltammogram in dichloromethane showed a reversible Ru-III-Ru-II couple at -0.55 V and an oxidation couple at 0.32 V.

  DOI：

  10.1039/dt9950002215
• 作为产物：
  描述：

  在 O₂ 、 LiCl 作用下， 以 丙酮 为溶剂， 生成
  参考文献：
  名称：

  Synthesis, crystal structure and catalytic activities of [RuIII(bbpc)(PPh3)Cl][H2bbpc = 1,2-bis(4-tert-butylpyridine-2-carboxamido)-4,5-dichlorobenzene]

  摘要：

  The compound H(2)bbpc [1,2-bis(4-tert-butylpyridine-2-carboxamido)-4,5-dichlorobenzene], which has good solubility in organic solvents, has been prepared. Reaction of [Ru(PPh(3))(3)Cl-2] with H(2)bbpc in ethanol and in the presence of triethylamine gave [Ru-II(bbpc)(PPh(3))Cl], the crystal structure of which has been determined. This complex is an active catalyst for alkene epoxidation by PhlO, cyclopropanation of styrene by ethyl diazoacetate and aziridination of styrene by PhlNO(2)SC(6)H(4)Me-p. Its cyclic voltammogram in dichloromethane showed a reversible Ru-III-Ru-II couple at -0.55 V and an oxidation couple at 0.32 V.

  DOI：

  10.1039/dt9950002215