[In(tetra-(pentafluorophenyl)porphyrin | 56398-55-1

• 英文名称: [In(tetra-(pentafluorophenyl)porphyrin
• CAS: 56398-55-1
• 化学式: C₄₄H₈ClF₂₀InN₄
• 分子量: 1122.82
• InChiKey: HNIOGBBMAJKOKH-VTVSBRCESA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Na[Mo(CO)3(cyclopentadienyl)] 、 [In(tetra-(pentafluorophenyl)porphyrin 以96%的产率得到
  参考文献：
  名称：

  金属-金属键在卟啉环上延伸：III。新型金属-金属键合卟啉铟（TBPP）In-ML和（5FP）In-ML的合成和光谱研究

  摘要：

  两个新的金属-金属键合铟卟啉配合物系列（TBPP）In-ML和（5FP）In-ML，其中TBPP是5,10,15,20-四（3,5-di-t-丁基苯基）卟啉和5FP是5,10,15,20-四（2,3,4,5,6-五氟苯基）卟啉的二价阴离子，ML是Mn（CO）5，Mo（CO）3 Cp和Co除了（OEP）In-ML和（TPP）In-ML之外，还合成了（CO）4。与（OEP）In-ML和/或（TPP）In-ML相比，这些新型的金属-金属键结合的卟啉配合物对有机溶剂具有更高的溶解度或更高的光化学稳定性。（P）In-Co（CO）4配合物，其中P表示所有这些卟啉配体，是通过（P）In-Cl与LiCo 3（CO）10反应以几乎定量的产率获得的。这些卟啉配合物显示出超类的典型紫外-可见光谱。吸收光谱的分析揭示了（5FP）In-ML配合物的异常特征。对于相同的ML，（P）In-ML配合物中CO配体的17 O和13

  DOI：

  10.1016/0022-328x(92)83180-p
• 作为产物：
  描述：

  tetrakis(pentafluorophenyl)porphyrin 、 氯化铟 在 CH₃COONa 作用下， 以 溶剂黄146 为溶剂， 以85%的产率得到[In(tetra-(pentafluorophenyl)porphyrin
  参考文献：
  名称：

  Perhalogenated porphyrinic derivatives with indium and thallium: the X-ray structures of (β-Cl4TPP)Tl(Cl), (β-Cl4TPP)In(Cl) and (TpFTPP)Tl(Cl)

  摘要：

  The synthesis and spectroscopic characterization of new substituted porphyrinate complexes are reported. The investigated compounds are represented by the formula (Porph)M(Cl) where Porph are TpFPP, TPyP, beta-Cl4TPP, beta-Cl8TPP or beta-Cl4TPP, and M=In or Tl.UV-Vis and NMR spectroscopies of the title complexes confirm the proposed molecular formula and are described extracting all plausible information. The study is completed by three X-ray structures of (beta-Cl4TPP)Tl(Cl), (beta-Cl4TPP)In(Cl) and (TpFTPP)TI(Cl).Compounds (beta-Cl4TPP)Tl(Cl) and (beta-Cl4TPP)In(Cl) are isostructural and they were treated in a similar way. The chloride substituents on the porphyrin core were found to be disordered in both compounds and they were refined anisotropically with occupation factors free to vary. The porphyrin core is saddle distorted while there is no twist distortion as judged by the large values of the dihedral angles formed between the phenyl rings and the C20N4 mean plane. In compound (TpFTPP)ln(Cl), the dihedral angles between the pentafluorophenyl rings and C20N4 are very close to the ideal value of 90degrees. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2004.04.010