The reactivity of HRu3(CO)9C2·CMe3. The hydrogenation of coordinated t-butyl-acetylene to neo-hexane and the crystal structure of the intermediate trihydride H3Ru3(CO)9C·CH2·CMe3
Multi-site bonded hydrocarbyls on osmium clusters. The reactions of hydridoacetylide and hydridovinylidene-osmium clusters with [(η-C5H5)Ni(CO)]2 and of (η-C5H5)2Ni2(HC2But) with osmium carbonyls. Synthesis and crystal structure of (η-C5H5)Ni(μ-H)Os3(CO)9(μ4-η2-CCHBut)
The heterometallic cluster (η-C5H5)Ni(μ-H)Os3(CO)9(CCHBut) has been obtained in low yield by treating hydridoacetylide- or hydridovinylidene-osmium clusters with [(C5H5)Ni(CO)]2 under hydrogen. The structure of this complex has been determined by X-ray methods.
的异金属簇(η-C 5 H ^ 5)的Ni(μ-H)O的3(CO)9(CCHBu吨通过用[(C hydridoacetylide-或hydridovinylidene -锇簇)已在低收率获得5 ħ 5)Ni(CO)] 2在氢下。该配合物的结构已经通过X射线方法确定。
Hajela, Sharad; Novak, Bruce M.; Rosenberg, Edward, Organometallics, 1989, vol. 8, # 2, p. 468 - 475
作者:Hajela, Sharad、Novak, Bruce M.、Rosenberg, Edward