| 1071591-22-4

• CAS: 1071591-22-4；1071875-38-1
• 化学式: C₁₆H₁₂Cl₃FN₂Pt
• 分子量: 552.722
• InChiKey: UANHXJZGCIPLRN-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-(4-fluorobenzene-6-id-1-yl)pyridine;platinum(2+);pyridine;chloride 、 (二氯碘)-苯 以 氯仿 、 丙酮 为溶剂， 生成
  参考文献：
  名称：

  Platinum(IV) Complexes: C−H Activation at Low Temperatures

  摘要：

  The oxidation of square-planar cyclometalated Pt(II) phenylpyridine species using the electrophilic chlorine based oxidant PhICl2 has been studied. Rapid oxidations are observed in chloroform solvent at -40 degrees C leading to single products. In acetone solvent isomeric forms of the product are formed, and these are observed to isomerize at around -10 degrees C. The oxidation of a complex with an uncyclometalated pendant arm resulted in the very rapid cyclometalation of that arm by the resulting electrophilic Pt(IV) species.

  DOI：

  10.1021/om800583c