A visible light-driven catalytic cycle for hydrocarboxylation of alkenes with CO2 was established using a combination of a Rh(i) complex as a carboxylation catalyst and [Ru(bpy)3]2+ (bpy = 2,2′-bipyridyl) as a photoredox catalyst.
使用Rh(
i)复合物作为羧化催化剂和[Ru(bpy)
3]
2+ (bpy = 2,2′-联
吡啶)作为光氧化还原催化剂,建立了一种可见光驱动的烯烃与CO
2的羧化催化循环。