bis(μ-2-(3-phenylpropenoyl)phenolato)bis(methyl)bis(trimethylphosphine)nickel(II) | 864759-31-9

• 英文名称: bis(μ-2-(3-phenylpropenoyl)phenolato)bis(methyl)bis(trimethylphosphine)nickel(II)
• CAS: 864759-31-9；864876-42-6
• 化学式: C₃₈H₄₆Ni₂O₄P₂
• 分子量: 746.108
• InChiKey: RSKLHJYOUJLLFU-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  bis(μ-2-(3-phenylpropenoyl)phenolato)bis(methyl)bis(trimethylphosphine)nickel(II) 、 三甲基膦 以 乙醚 为溶剂， 以58%的产率得到trans-methyl-2-(3-phenyl-2,3-η2.-propenoyl)phenolatobis(trimethylphosphine)nickel(II)
  参考文献：
  名称：

  α,β-Unsaturated Carbonyl Compounds as Hard/Soft Chelating Ligands in Methyl Nickel Phenolates and the Structure of trans-Methyl-2-(3-phenyl-2,3-η²- propenoyl)phenolatobis(trimethylphosphine)nickel(II)

  摘要：

  Phenolato functions of chalcone type compounds may replace both methoxo bridges in dinuclear methyl nickel complexes without utilizing the aldehyde functions. Cleavage of phenolato-bridged nickel(II) centers in square planar coordination geometry by addition of trimethylphosphine affords mononuclear methylnickel complexes of coordination number five. The trimethylphosphine-supported trigonal bipyramidal methyl nickel(II) complex has a hard/soft chelating ligand with a phenolato oxygen atom and a pi-coordinated olefin functional group. The chemical reactivity of complexes with these novel hard/soft chelating ligands remains to be clarified.

  DOI：

  10.1021/om050051a
• 作为产物：
  描述：

  (2E)-1-(2-羟基苯基)-3-苯基-2-丙烯-1-酮 、 trans-chloro(methyl)bis(trimethylphosphane)nickel(II) 以 乙醚 为溶剂， 以19%的产率得到bis(μ-2-(3-phenylpropenoyl)phenolato)bis(methyl)bis(trimethylphosphine)nickel(II)
  参考文献：
  名称：

  α,β-Unsaturated Carbonyl Compounds as Hard/Soft Chelating Ligands in Methyl Nickel Phenolates and the Structure of trans-Methyl-2-(3-phenyl-2,3-η²- propenoyl)phenolatobis(trimethylphosphine)nickel(II)

  摘要：

  Phenolato functions of chalcone type compounds may replace both methoxo bridges in dinuclear methyl nickel complexes without utilizing the aldehyde functions. Cleavage of phenolato-bridged nickel(II) centers in square planar coordination geometry by addition of trimethylphosphine affords mononuclear methylnickel complexes of coordination number five. The trimethylphosphine-supported trigonal bipyramidal methyl nickel(II) complex has a hard/soft chelating ligand with a phenolato oxygen atom and a pi-coordinated olefin functional group. The chemical reactivity of complexes with these novel hard/soft chelating ligands remains to be clarified.

  DOI：

  10.1021/om050051a