[2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)2H | 477178-15-7

• 英文名称: [2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)2H
• CAS: 477178-15-7
• 化学式: C₂₇H₂₃NO₂Ru
• 分子量: 494.555
• InChiKey: BZWUAIUSIAVLNO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)2H 在 benzaldehyde 作用下， 以 氘代四氢呋喃 为溶剂， 生成 ([2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)(μ-CO))2
  参考文献：
  名称：

  Protonated Aminocyclopentadienyl Ruthenium Hydride Reduction of Benzaldehyde and the Conversion of the Resulting Ruthenium Triflate to a Ruthenium Hydride with H₂ and Base

  摘要：

  Reaction of N-phenyl-2,5-dimethyl-3,4-diphenylcyclopenta-2,4-dienimine (6) with Ru3CO12 formed two isomers of {[2,5-Me-2-3,4-Ph-2(eta(5) -C4CNHPh)]Ru(CO)(mu-CO)}(2) (8-trans and 8-cis). Photolysis of 8 under a H-2 atmosphere led to the formation of the aminocyclopentadienyl ruthenium hydride [2,5-Me-2-3,4-Ph-2(eta(5)-C4CNHPh)]Ru(CO)(2)H (9-H). 9-H reduced benzaldehyde slowly at 75 degreesC to give benzyl alcohol and 8. Protonation of 9-H with triflic acid produced {[2,5-Me-2-3,4-Ph-2(eta(5)-C4CNH2Ph)]Ru(CO)(2)H}OTf (11-H), which reacted rapidly with benzaldehyde at -80 degreesC to give benzyl alcohol and [2,5-Me-2-3,4-Ph-2(eta5-C4CNHPh)]Ru(CO)(2)OTf(9-OTf). Reaction of 9-OTf with H2 and base led to the re-formation of 9-H. These reactions provide the transformations required for a catalytic cycle for hydrogenation of aldehydes.

  DOI：

  10.1021/om020507d
• 作为产物：
  描述：

  ([2,5-Me2-3,4-Ph2(η5-C4CNH2Ph)]Ru(CO)2H)OTf 在 THF 作用下， 以 二氯甲烷 为溶剂， 生成 [2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)2H
  参考文献：
  名称：

  Protonated Aminocyclopentadienyl Ruthenium Hydride Reduction of Benzaldehyde and the Conversion of the Resulting Ruthenium Triflate to a Ruthenium Hydride with H₂ and Base

  摘要：

  Reaction of N-phenyl-2,5-dimethyl-3,4-diphenylcyclopenta-2,4-dienimine (6) with Ru3CO12 formed two isomers of {[2,5-Me-2-3,4-Ph-2(eta(5) -C4CNHPh)]Ru(CO)(mu-CO)}(2) (8-trans and 8-cis). Photolysis of 8 under a H-2 atmosphere led to the formation of the aminocyclopentadienyl ruthenium hydride [2,5-Me-2-3,4-Ph-2(eta(5)-C4CNHPh)]Ru(CO)(2)H (9-H). 9-H reduced benzaldehyde slowly at 75 degreesC to give benzyl alcohol and 8. Protonation of 9-H with triflic acid produced {[2,5-Me-2-3,4-Ph-2(eta(5)-C4CNH2Ph)]Ru(CO)(2)H}OTf (11-H), which reacted rapidly with benzaldehyde at -80 degreesC to give benzyl alcohol and [2,5-Me-2-3,4-Ph-2(eta5-C4CNHPh)]Ru(CO)(2)OTf(9-OTf). Reaction of 9-OTf with H2 and base led to the re-formation of 9-H. These reactions provide the transformations required for a catalytic cycle for hydrogenation of aldehydes.

  DOI：

  10.1021/om020507d
• 作为试剂：
  描述：

  4-叠氮苯甲酸甲酯 、 1-(叠氮甲基)-4-甲氧基苯 在 [2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)2H 作用下， 反应 16.0h， 以92%的产率得到4-氨基苯甲酸甲酯
  参考文献：
  名称：

  苄基叠氮化物和芳基叠氮化物之间的氧化还原反应：芳基腈和苯胺的协同合成†

  摘要：

  描述了苄基叠氮化物和芳基叠氮化物之间独特且新颖的反应，其以光活化的二钌配合物催化同时合成芳基腈和苯胺。N-未取代的亚胺（NH-亚胺）首先由叠氮化物生成，然后是NH-亚胺与芳基叠氮化物之间的氢转移反应。在中性和温和的反应条件下合成了多种芳基腈和苯胺。

  DOI：

  10.1039/c6ob02615j