trans-[Pt(o-NC5H4CCPh)(SEt2)Cl2] | 158881-84-6

• 英文名称: trans-[Pt(o-NC5H4CCPh)(SEt2)Cl2]
• CAS: 158881-84-6
• 化学式: C₁₇H₁₉Cl₂NPtS
• 分子量: 535.397
• InChiKey: WNQFUOYTOHHHHR-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  trans-[Pt(o-NC5H4CCPh)(SEt2)Cl2] 、 二乙胺 以 氯仿 为溶剂， 以>99的产率得到trans-[Pt(cis-(o-NC5H4CHC(Ph)(NEt2)))(NEt2)Cl2]
  参考文献：
  名称：

  Cis and trans nucleophilic additions on CC bonds assisted by Pt(II) complexes. X-ray crystal structure of trans-{Pt[cis-(o-NC5H4)CHC(Ph)(NEt2)]Cl2(HNEt2)}

  摘要：

  The reaction between PtCl2(PhCN)2 and N,N-dimethyl phenyl propargyl amine (1) affords trans-[Pt(N(Me2)CH2C=CPh)(NCPh)Cl2] (3) which formally undergoes trans-Cl- addition onto its C=C bond to give [Pt(C(Ph) = C(Cl)CH2NMe2)(NCPh)Cl] (4). On the other hand, the cis-nucleophilic addition product trans-{Pt[cis-(o-NC5H4) CH=C(Ph)(NEt2)]Cl2(HNEt2)} (6) was obtained quantitatively from the reaction of a large excess of diethylamine with trans-[Pt(o-NC5H4)CH=C(Ph)(SEt2)Cl2] (5).

  DOI：

  10.1016/s0277-5387(00)83103-4
• 作为产物：
  描述：

  2-(2-苯基乙炔基)吡啶 、 trans-dichlorobis(diethyl sulfide)platinum(II) 以 四氢呋喃 为溶剂， 以97%的产率得到trans-[Pt(o-NC5H4CCPh)(SEt2)Cl2]
  参考文献：
  名称：

  Cis and trans nucleophilic additions on CC bonds assisted by Pt(II) complexes. X-ray crystal structure of trans-{Pt[cis-(o-NC5H4)CHC(Ph)(NEt2)]Cl2(HNEt2)}

  摘要：

  The reaction between PtCl2(PhCN)2 and N,N-dimethyl phenyl propargyl amine (1) affords trans-[Pt(N(Me2)CH2C=CPh)(NCPh)Cl2] (3) which formally undergoes trans-Cl- addition onto its C=C bond to give [Pt(C(Ph) = C(Cl)CH2NMe2)(NCPh)Cl] (4). On the other hand, the cis-nucleophilic addition product trans-{Pt[cis-(o-NC5H4) CH=C(Ph)(NEt2)]Cl2(HNEt2)} (6) was obtained quantitatively from the reaction of a large excess of diethylamine with trans-[Pt(o-NC5H4)CH=C(Ph)(SEt2)Cl2] (5).

  DOI：

  10.1016/s0277-5387(00)83103-4