[Cp(CO)2FeCH2(CH2)2CH=CH2] | 34788-97-1

• 英文名称: [Cp(CO)2FeCH2(CH2)2CH=CH2]
• CAS: 34788-97-1
• 化学式: C₁₂H₁₄FeO₂
• 分子量: 246.089
• InChiKey: LCSCJHAXMCPCGL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Cp(CO)2FeCH2(CH2)2CH=CH2] 、 水 在 sodium hydroxide 、 硼烷四氢呋喃络合物 、 双氧水 作用下， 以 四氢呋喃 、 水 为溶剂， 以64%的产率得到
  参考文献：
  名称：

  The synthesis and characterisation of a new series of ω-hydroxy-alkyl complexes of iron

  摘要：

  omega-Hydroxy-alkyl compounds of the type, [Fe(eta(5)-C5R5){(CH2)(n)CH2OH}(CO)(2)] (R=H and Me, n =2-5, 7) were prepared by the oxidative hydroboration of the appropriate eta(1)-alkenyl compounds of the general formula, [Fe(eta(5)-C5R5){(CH2)(n-1)CH=CH2}(CO)(2)]. All new compounds were characterised by infrared, H-1 and C-13 NMR spectroscopy as well as mass spectrometry. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(99)00252-1
• 作为产物：
  描述：

  在 sodium iodide 作用下， 以 丙酮 为溶剂， 以69%的产率得到[Cp(CO)2FeCH2(CH2)2CH=CH2]
  参考文献：
  名称：

  Carbon-carbon bond formation by condensation of CpFe(CO)2(.eta.1-allyl) complexes with CpFe(CO)2(.eta.2-olefin) cations. Regio- and stereospecificity, sequential reactions leading to cycloadducts

  摘要：

  DOI：

  10.1021/ja00543a022

文献信息

• Synthesis and characterization of transition metal stabilized carbocations of the types [Cp∗(CO)2Fe{μ-(CnH2n−1}M(CO)xCp]PF6 (x=2, M=Fe or Ru; x=3, M=W, Cp∗=η5-C5(CH3)5; Cp=η5-C5H5; n=3–6) and [Cp(CO)2Ru{μ-(CnH2n−1)}W(CO)3Cp]PF6 (n=3–5) and the crystal structures of the complexes [Cp∗(CO)2Fe(CH2)3Ru(CO)2Cp], [Cp∗(CO)2Fe(CH2)5Ru(CO)2Cp], [Cp∗(CO)2Fe-(CH2)5W(CO)3Cp], and [Cp(CO)2Ru(CH2)5W(CO)3Cp]
  作者：Evans O. Changamu、Holger B. Friedrich、Melanie Rademeyer

  DOI：10.1016/j.jorganchem.2007.02.016

  日期：2007.5

  reported elsewhere. The structures of the precursor complexes [Cp∗(CO)2Fe(CH2)3Ru-(CO)2Cp] (1), [Cp∗(CO)2Fe(CH2)5Ru-(CO)2Cp] (2), [Cp∗(CO)2Fe(CH2)5W(CO)3Cp] (3), and [Cp(CO)2Ru (CH2)5W(CO)3Cp] (4), have been confirmed by single crystal X-ray crystallography. The structure of [Cp∗(CO)2Fe(CH2)3Ru(CO)2Cp] is compared with that of its corresponding cationic complex, [Cp∗(CO)2Feμ-(C3H5)}Ru(CO)2Cp]PF6.

  混合配体配合物的[CP * （CO）2的Fe（CH 2）ñ M（CO）X的CP]（X  = 2，M = Fe或钌; X  = 3，M = W中，CP *  =η 5 - ç 5（CH 3）5 ; CP =η 5 -C 5 H ^ 5 ; ñ  = 3-6），键入我，与一当量氢化物提取器的Ph反应3 CPF 6，得到的过渡金属稳定化的碳阳离子配合物[ CP ∗（CO）2 Fe μ-（C nH 2 n -1）} M（CO）x CP] PF 6。同样，新的II型异质双金属配合物[CP（CO）2 Ru μ-（C n H 2 n -1）} W（CO）3 CP]与Ph 3 CPF 6反应生成碳正离子配合物[CP（ CO）2 Ru μ-（C n H 2 n -1）} W（CO）3 CP] PF 6。光谱数据表明，氢化物从亚甲基β选择性地发生到与CP ＊配体连接的金属原子上我很复杂。在式II的复合物
• Reactivity studies on some η1-alkenyl complexes of iron
  作者：Leone Hermans、Selwyn F. Mapolie

  DOI：10.1016/s0277-5387(96)00295-1

  日期：1997.1

  The eta(1)-alkenyl complexes [eta(5)-C5H5(CO)(2)Fe(CH2)(n)CH=CH2] (n = 2 and 3) have been prepared by the reaction of Na[eta(5)-C5H5(CO)(2)Fe] with 4-bromo-1-butene and 5-bromo-1-pentene respectively. The reactivity of the sigma-olefin complexes in hydrogenation, hydroboration and hydroformylation reactions are reported as are reactions with Lewis acids such as TiCl4 and the electrophile HCl. Copyright (C) 1996 Elsevier Science Ltd