dysprosium phthalocyanine chloride | 56604-52-5

• 英文名称: dysprosium phthalocyanine chloride
• CAS: 56604-52-5
• 化学式: C₃₂H₁₆ClDyN₈
• 分子量: 710.486
• InChiKey: GSWCCZFEZONIFO-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  dysprosium phthalocyanine chloride 在 溶剂黄146 作用下， 以 乙醇 、 溶剂黄146 为溶剂， 生成 酞青
  参考文献：
  名称：

  Mutual Influence of Ligands and Reactivity of Gd and Dy Acidophthalocyaninate Complexes

  摘要：

  The results of the kinetic study of dissociation of Gd(III) and Dy(III) complexes with phthalocyanine of the composition (X)LnPc (X is single-charged acido ligand) with isolation of macrocyclic ligand depending on the temperature, composition of mixed ethanol-acetic acid solvent, and the nature of acido ligand are presented. The total kinetic equations, the rate constants, and activation parameters of dissociation reaction are determined. The stoichiomeric mechanism is suggested for the complex dissociation involving the limiting elementary reaction between acetic acid molecule and the complex that occurs as the chelate salt (X)LnPc or the outer-sphere complex [(HOAc)LnPc]X-+(-). The state of metal phthalocyaninate at the reaction slow stage is shown to be determined by the electronic structure of the metal cation, the strength of binding of the axial ligand, and by its cis-effect on the metal bonds with macrocycle.

  DOI：

  10.1023/b:ruco.0000040727.21739.44
• 作为产物：
  描述：

  氯化镝(III) 、 酞青 在 正丁基锂 作用下， 以 二甲基亚砜 为溶剂， 以91%的产率得到dysprosium phthalocyanine chloride
  参考文献：
  名称：

  Subbotin, N. B.; Tomilova, L. G.; Kostromina, N. A., Journal of general chemistry of the USSR, 1986, vol. 56, p. 345 - 348

  摘要：

  DOI：

文献信息

• Synthesis of a Series of Monophthalocyaninato Cyclen Heavy Lanthanide(III) Complexes with Tetragonal Symmetry
  作者：Kazuro Kizaki、Motoshi Uehara、Akira Fuyuhiro、Takamitsu Fukuda、Naoto Ishikawa

  DOI：10.1021/acs.inorgchem.7b02505

  日期：2018.1.16

  A series of the new monophthalocyaninato lanthanide complexes, [Ln(Pc)(cyclen)]Cl (Ln = Y, Tb, Dy, Ho, Er, Tm, and Yb; Pc = phthalocyaninato; cyclen = 1,4,7,10-tetraazacyclododecane) was synthesized and characterized. The crystallographic study of monophthalocyaninato complexes with a capping macrocyclic ligand having no π-conjugation while keeping the 4-fold symmetry is presented for the first time

  一系列新的单酞菁基镧系元素络合物[Ln（Pc）（cycln）] Cl（Ln = Y，Tb，Dy，Ho，Er，Tm和Yb; Pc =酞菁基;周期数= 1,4,7,10 -四氮杂环十二烷）的合成和表征。首次提出了单酞菁与配合物的结晶学研究，该配合物具有不具有π共轭作用，同时保持4倍对称性的封端大环配体。所有六个络合物在的四方结构进行结晶，我4毫米间隔基。除此之外，Tb络合物还表现出P 1̅空间群的三斜晶体结构。所有的络合物都是同构的，其中Pc和cyclen都与Ln 3+配位产生八坐标方棱柱形几何图形。在四方晶体中，Pc和cycln配体之间的偏角为45°，在三斜晶中为41.5°。Pc配体侧的金属-氮键长度短于环烯侧，这可能是由于配体电荷和空间因子的差异所致。